Exam 3 Flashcards
Covalent Bond
Bond where atoms share electrons
Bond lengths - = ≡
triple(≡) = shortest
single(-) = longest
Bond energy (lowest to highest)
single(-) = lowest
triple(≡) = highest
Electronegativity trend
increases up and to the right
Ionic bond
atoms lose and gain electrons and are bonded by pos/neg attraction
Polar bond
Electrons are not shared equally (one atom pulls the electron more than the other because it is more electronegative)
Atoms greater than or equal to what atomic number can break the octet rule
15
Formal charge
of electrons around the atom in a lewis structure (- bond = 1) compared to the # of valence electrons that atom brings
Resonance structures
A lewis structure that represents the possibility of different locations where bonds can exist
Sum of individual formal charges =
Total charge of the molecule
VSEPR
Valence Shell Electron Pair Repulsion (Electrons want to get as far away from each other as possible)
Geometry (in lewis structures)
Structure represented by bonds and lone pairs
Shape (lewis structure)
Structure represented by only the bonds
2 Bonds (find geometry, bond angle, and hybridization)
Geometry = Linear
Bond angle = 180
Hybridization = sp
3 bonds (find geometry, bond angle, and hybridization)
Geometry = trigonal planar
Bond angle = 120
Hybridization = sp2
4 bonds (find geometry, bond angle, and hybridization)
Geometry = tetrahedral
Bond angle = 109.5
Hybridization = sp3
5 bonds (find geometry, bond angle, and hybridization)
Geometry = trigonal bipyramid
Bond angle = 90 120
Hybridization = sp3d
6 bonds (find geometry, bond angle, and hybridization)
Geometry = octahedron
Bond angle = 90
Hybridization = sp3d2
Lone pairs, double bonds, and triple bonds do what to bond angles
They all repel more than single bonds which will make the bond angles smaller depending on how you look at it
Axial plane
Up and down/side-to-side linear AXIS
Equitorial plane
Flat plane, similar to an equator
Pi bond
Double or triple bond where orbitals overlap side to side
Sigma bond
Single bond where orbitals overlap head to head