Energy Changes (P1) Flashcards
Exothermic vs endothermic
Exo gives out heat
Endo takes in heat
Reaction profile for endothermic
Increases a lot to the activation energy and decreases a bit to the products energy
Reaction profile for exothermic
Increases a bit to activation energy, decreases a lot to product energy
When is energy taken in and absorbed in relation to bonds?
Taken in to break, released when made
Electrical cell
Two conductive metals in an electrolyte (solution with ions)
Electrodes are connected by a wire to let charge flow
(Electrolysis)
When is the p.d. of a cell greatest?
When the electrodes have the greatest difference in reactivity
Hydrogen fuel cells
Electrolyte is acid
Hydrogen makes h+ which cross the acid and the e- go through the wire
They then become hydrogen again
Each reacts with 2 oxygen atoms to make water
Releases oxygen and heat
Why does breaking bonds release energy
Because the elements are more stable
How to calculate energy change?
Reactants-products
Multiply by subscript but not moles
Hydrogen fuel cell negative electrode
2H2 —> 4H+ +4e-
Hydrogen fuel cell positive electrode
O2 + 4H+ + 4e- —> 2H2O
Overall hydrogen fuel cell reaction
2H2 + O2 —> 2H2O
Hydrogen fuel cell advantages vs rechargeable
Produce electricity until hydrogen runs out, rechargeables need recharging
Hydrogen maintains efficiency, rechargeables are less after each charging cycle
Water produced can be useful
Hydrogen fuel cell disadvantage vs rechargeable
Hydrogen is explosive, rechargeables cannot explode unless badly made
Rechargeables produce a higher p.d., you need several hydrogen fuel cells
Endothermic examples
Boiling
Melting
Evaporating
Photosynthesis