DMS Flashcards
What are the components of composite?
Dimethylacrylate
Camphorquinone
Silane coupling agent
Glass filler
Soft resin
Function of the dimethylacrylate and silane coupling agent?
DMA = forms two bonds rather than one in resin
SCA = forms bond between resin and the hard filler
Function of camphorquinone and soft resin and the glass filler?
Cam = light activated free radical addition polymerisation
SR = polymerised by Cam
Hard filler = added mechanical properties
What are the components of amalgam?
Mercury
Silver
Tin
Copper
Zinc
What are the three gamma phases?
Gamma is unreacted material of mercury and tin
Gamma 1 is strong, corrosion resistant silver-mercury
Gamma 2 is very weak corrosive tin-mercury
What do mercury and zinc function as in amalgam?
Mercury is a liquid so it is workable
Zinc is an oxidiser
What does silver do in amalgam?
Silver adds strength, reduces creep too, also increases setting strength
What does copper do in amalgam
Copper enriched amalgam has less gamma 2 phase
So less creep and corrosion, and stronger properties
What does tin function as in amalgam
Tin contributes to small amounts of corrosion
This helps seal restoration margins however causes creep
What are the three setting stages for GIC
Dissolution, gelation and hardening
Describe dissolution
Polyacrylic acid attacks glass particles releasing metal ions Ca, Na, Al, and F
Describe gelation.
Calcium bivalve to ions crosslink between poly salt chains.
Calcium can bind to same chain with both links so does not always create increased strength with every molecule
Describe hardening
Trivalent aluminium ions crosslink between 3 chains and harden the substance, increasing strength
How does GIC bind to enamel?
Calcium in enamel cross links with polyacrylic acid in the GIC
What are the components of ZOE?
Zinc oxide base powder
Eugenol and glycol liquid with some water