Chemistry Final Flashcards

1
Q

organic compound properties

A

covalent
non polar
low melting
low boiling
high flammability
not soluble in water- unless polar present

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2
Q

inorganic compound properties

A

ionic bond
ionic polarity
high boiling
high melting
low flammability
soluble in water

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3
Q

does organic or inorganic have fewer compounds

A

inorganic

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4
Q

hydrogenation

A

alkene + H2 > alkane

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5
Q

hydration

A

alkene + h2O > alcohol

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6
Q

polymerization

A

alkene + high temp pressure > polymer

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7
Q

phenol

A

OH on top of ring

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8
Q

thiol

A

contain SH group

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9
Q

why are short chain alcohols water soluble

A

they can hydrogen bond

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10
Q

3-pentanol undergoes oxidation, product is

A

ketone

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11
Q

`

A
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12
Q

product of oxidation of secondary alcohol

A

Ketone

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13
Q

product of dehydration of 1-propanol

A

alkene

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14
Q

major product of dehydration of 2-methycyclobutanol

A

1-methylcyclobutene

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15
Q

oxidation of alcohol

A

increase # of carbon-oxygen bonds

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16
Q

reduction of alcohol

A

decrease # of carbon-oxygen bonds

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17
Q

alcohol with 5 or more carbons

A

not soluble

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18
Q

alcohol with 4 carbons

A

slightly soluble

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19
Q

alcohol with 1-3 carbons

A

soluble

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20
Q

reduction of ketone

A

secondary alcohol

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21
Q

reduction of aldehyde

A

primary alcohol

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22
Q

oxidation of aldehyde

A

carboxylic acid

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23
Q

oxidation of primary alcohol

A

aldehyde, carboxylic acid

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24
Q

what does Benedicts reagent test for

A

aldehydes

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25
Q

Tollens’ test

A

aldehyde is oxidized and Ag+ is reduced

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26
Q

reaction of alcohol with aldehyde is

A

addition

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27
Q

ether

A

oxygen splits the carbon

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28
Q

hemiacetal

A

carbon bonded to one oxygen and one alcohol

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29
Q

acetal

A

carbon bonded to 2 oxygen groups

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30
Q

requirement of photosynthesis

A

sun, water, carbon dioxide

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31
Q

products of photosynthesis

A

carbohydrates and oxygen

32
Q

where do carbohydrates come from

A

carbohydrates contain hydrogen and oxygen in a 2:1 ratio

33
Q

functional groups in open chain forms of monosaccharides

A

hydroxyl an aldehyde or ketone

34
Q

Benedicts test of glucose would be

A

positive

35
Q

dissaccharide not a reducing sugar

A

sucrose

36
Q

disaccharide that occurs as breakdown of amylose

A

maltose

37
Q

carbohydrate produced as storage form energy in plants

A

amylopectin

38
Q

storage form of energy in humans

A

glycogen

39
Q

carbohydrate used for structural purposes by plants

A

cellulose

40
Q

polysaccharide composed of many glucose units linked by a(1-4) glycosidic bonds

A

amylose

41
Q

sugar containing glucose and galactose

A

lactose

42
Q

polysaccharide composed of glucose units joined by a(1-4) and a(1-6) glycosidic bonds

A

glycogen

43
Q

disaccharide that is a reducing sugar

A

lactose and maltose

44
Q

carbohydrate composed of glucose units joints by b(1-4) glycosidic bonds

A

cellulose

45
Q

sugar composed of glucose and fructose

A

sucrose

46
Q

table sugar

A

sucrose

47
Q

gives glucitol upon reduction

A

glucose

48
Q

gives galactose upon hydrolysis

A

lactose

49
Q

Product when carboxylic acid reacts with sodium hydroxide

A

carboxylate salt

50
Q

carboxylic acids are water soluble due to their

A

ability to hydrogen bond

51
Q

acid hydrolysis

A

water react with ester > carboxylic acid and alcohol

52
Q

saponification

A

ester undergoes hydrolysis > carboxylic salt and alcohol

53
Q

neutralization

A

weak - neutralized by strong base > carboxylic salt + water

54
Q

esterification

A

ester produced, carboxylic acid and alcohol react

55
Q

ester have…

A

pleasant odor
can undergo hydrolysis
formed from alcohol and carboxylic acid
lower boiling point than corresponding acid

56
Q

in a hydrolysis reaction

A

an ester reacts with H2O

57
Q

biomolecule soluble in organic solvents but not water

A

lipid

58
Q

fatty acid that is unsaturated is usually

A

from vegetable sources and liquid at room temp

59
Q

triglycerols are formed by

A

esterification

60
Q

triglycerols would be expected to be

A

saturated and a solid at room temp

61
Q

triglycerol reacts with strong base, products would be

A

glycerol and the sodium salt of the fatty acid

62
Q

triglycerol reacts with strong base it would be..

A

saponification

63
Q

alkanes

A

non polar
insoluble in water
less dense than water
flammable in the air
in crude oil

64
Q

combustion of alkanes

A

carbon - carbon single bonds are difficult to break, least reactive family of organic compounds

65
Q

alkense and alkynes

A

unsaturated hydrocarbons bc don’t contain max number of hydrogen atoms
react with hydrogen gas to become alkanes

66
Q

hydrogenation

A

hydrogen add to carbon atoms

67
Q

hydration

A

alkene react with water to form alcohol
OH goes to carbon with fewer hydrogen
Markonikov’s rule

68
Q

hydration

A

alkene react with water to form alcohol
OH goes to carbon with fewer hydrogen
Markonikov’s rule

69
Q

halogenation

A

halogen atoms (Cl or Br) add to carbon of double or triple bond, make single

70
Q

bromine added to alkane - red color

A

stay

71
Q

bromine added to alkene or alkyne - red color

A

disappears immediately

71
Q

bromine added to alkene or alkyne - red color

A

disappears immediately

72
Q

alcohol with two -OH groups

A

diol

72
Q

alcohol with two -OH groups

A

diol

73
Q

thiol odor

A

strong disagreeable odor
cheese, onion, garlic, oyster

74
Q

phenols

A

slightly soluble in water
-OH group to form hydrogen bonds with water