Chemistry Final Flashcards

1
Q

organic compound properties

A

covalent
non polar
low melting
low boiling
high flammability
not soluble in water- unless polar present

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2
Q

inorganic compound properties

A

ionic bond
ionic polarity
high boiling
high melting
low flammability
soluble in water

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3
Q

does organic or inorganic have fewer compounds

A

inorganic

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4
Q

hydrogenation

A

alkene + H2 > alkane

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5
Q

hydration

A

alkene + h2O > alcohol

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6
Q

polymerization

A

alkene + high temp pressure > polymer

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7
Q

phenol

A

OH on top of ring

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8
Q

thiol

A

contain SH group

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9
Q

why are short chain alcohols water soluble

A

they can hydrogen bond

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10
Q

3-pentanol undergoes oxidation, product is

A

ketone

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11
Q

`

A
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12
Q

product of oxidation of secondary alcohol

A

Ketone

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13
Q

product of dehydration of 1-propanol

A

alkene

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14
Q

major product of dehydration of 2-methycyclobutanol

A

1-methylcyclobutene

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15
Q

oxidation of alcohol

A

increase # of carbon-oxygen bonds

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16
Q

reduction of alcohol

A

decrease # of carbon-oxygen bonds

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17
Q

alcohol with 5 or more carbons

A

not soluble

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18
Q

alcohol with 4 carbons

A

slightly soluble

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19
Q

alcohol with 1-3 carbons

A

soluble

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20
Q

reduction of ketone

A

secondary alcohol

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21
Q

reduction of aldehyde

A

primary alcohol

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22
Q

oxidation of aldehyde

A

carboxylic acid

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23
Q

oxidation of primary alcohol

A

aldehyde, carboxylic acid

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24
Q

what does Benedicts reagent test for

A

aldehydes

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25
Tollens' test
aldehyde is oxidized and Ag+ is reduced
26
reaction of alcohol with aldehyde is
addition
27
ether
oxygen splits the carbon
28
hemiacetal
carbon bonded to one oxygen and one alcohol
29
acetal
carbon bonded to 2 oxygen groups
30
requirement of photosynthesis
sun, water, carbon dioxide
31
products of photosynthesis
carbohydrates and oxygen
32
where do carbohydrates come from
carbohydrates contain hydrogen and oxygen in a 2:1 ratio
33
functional groups in open chain forms of monosaccharides
hydroxyl an aldehyde or ketone
34
Benedicts test of glucose would be
positive
35
dissaccharide not a reducing sugar
sucrose
36
disaccharide that occurs as breakdown of amylose
maltose
37
carbohydrate produced as storage form energy in plants
amylopectin
38
storage form of energy in humans
glycogen
39
carbohydrate used for structural purposes by plants
cellulose
40
polysaccharide composed of many glucose units linked by a(1-4) glycosidic bonds
amylose
41
sugar containing glucose and galactose
lactose
42
polysaccharide composed of glucose units joined by a(1-4) and a(1-6) glycosidic bonds
glycogen
43
disaccharide that is a reducing sugar
lactose and maltose
44
carbohydrate composed of glucose units joints by b(1-4) glycosidic bonds
cellulose
45
sugar composed of glucose and fructose
sucrose
46
table sugar
sucrose
47
gives glucitol upon reduction
glucose
48
gives galactose upon hydrolysis
lactose
49
Product when carboxylic acid reacts with sodium hydroxide
carboxylate salt
50
carboxylic acids are water soluble due to their
ability to hydrogen bond
51
acid hydrolysis
water react with ester > carboxylic acid and alcohol
52
saponification
ester undergoes hydrolysis > carboxylic salt and alcohol
53
neutralization
weak - neutralized by strong base > carboxylic salt + water
54
esterification
ester produced, carboxylic acid and alcohol react
55
ester have...
pleasant odor can undergo hydrolysis formed from alcohol and carboxylic acid lower boiling point than corresponding acid
56
in a hydrolysis reaction
an ester reacts with H2O
57
biomolecule soluble in organic solvents but not water
lipid
58
fatty acid that is unsaturated is usually
from vegetable sources and liquid at room temp
59
triglycerols are formed by
esterification
60
triglycerols would be expected to be
saturated and a solid at room temp
61
triglycerol reacts with strong base, products would be
glycerol and the sodium salt of the fatty acid
62
triglycerol reacts with strong base it would be..
saponification
63
alkanes
non polar insoluble in water less dense than water flammable in the air in crude oil
64
combustion of alkanes
carbon - carbon single bonds are difficult to break, least reactive family of organic compounds
65
alkense and alkynes
unsaturated hydrocarbons bc don't contain max number of hydrogen atoms react with hydrogen gas to become alkanes
66
hydrogenation
hydrogen add to carbon atoms
67
hydration
alkene react with water to form alcohol OH goes to carbon with fewer hydrogen Markonikov's rule
68
hydration
alkene react with water to form alcohol OH goes to carbon with fewer hydrogen Markonikov's rule
69
halogenation
halogen atoms (Cl or Br) add to carbon of double or triple bond, make single
70
bromine added to alkane - red color
stay
71
bromine added to alkene or alkyne - red color
disappears immediately
71
bromine added to alkene or alkyne - red color
disappears immediately
72
alcohol with two -OH groups
diol
72
alcohol with two -OH groups
diol
73
thiol odor
strong disagreeable odor cheese, onion, garlic, oyster
74
phenols
slightly soluble in water -OH group to form hydrogen bonds with water