Chemical Bonding Flashcards

1
Q

What is chemical bonding?

A

Chemical bonding is the study of the force of attraction that holds atoms or ions together within a molecule or between molecules to form a substance.

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2
Q

What is the difference between intramolecular and intermolecular bonds?

A

Intramolecular bonds occur within a molecule, while intermolecular bonds occur among different molecules.

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2
Q

What type of electrons take part in chemical bonding?

A

Valence electrons, which are the electrons in the outer shell of an atom.

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3
Q

What are the four types of chemical bonds?

A

1) Electrovalent/Ionic bonding 2) Covalent bonding
3) Coordinate covalent/Dative bonding
4) Metallic bonding.

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3
Q

What is the main aim of chemical bonding?

A

The main aim of chemical bonding is to attain a stable noble gas octet or duplet configuration.

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3
Q

What is the octet rule?

A

The octet rule states that an atom will continue to lose, gain, or share electrons until it has eight electrons in its outermost shell.

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4
Q

What is the duplet rule and which elements follow it?

A

The duplet rule states that atoms will aim to have two electrons in their valence shell. Hydrogen and Helium follow the duplet rule.

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5
Q

What is electrovalent or ionic bonding?

A

Ionic bonding involves the transfer of electrons from a metal to a non-metal, resulting in the formation of positive and negative ions.

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6
Q

What are the properties of electrovalent compounds?

A

Electrovalent compounds are usually crystalline, have high melting and boiling points, conduct electricity in molten or aqueous states, and are soluble in polar solvents but insoluble in non-polar solvents.

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7
Q

What is covalent bonding?

A

Covalent bonding involves the sharing of electrons between two non-metal atoms.

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8
Q

What is a homonuclear molecule?

A

A homonuclear molecule is formed between atoms of the same element, resulting in a non-polar covalent bond.

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8
Q

What are the properties of covalent compounds?

A

Covalent compounds usually exist as gases, liquids, or solids, do not conduct electricity or heat, and are non-electrolytes.

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9
Q

What is a heteronuclear molecule?

A

A heteronuclear molecule is formed between atoms of different elements and may result in a polar or non-polar covalent bond depending on the symmetry of the molecule.

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10
Q

What is a dative bond?

A

A dative bond is a type of bond where a lone pair of electrons is donated by one atom to another atom that requires electrons to complete its valence shell.

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11
Q

What is a polar covalent bond?

A

A polar covalent bond occurs when there is an unequal sharing of electrons between atoms, leading to partial positive and negative charges.

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12
Q

Give examples of compounds with dative bonding.

A

Examples include ammonium ion (NH4+), hydronium ion (H3O+), and BF3-NH3 complex.

13
Q

What is metallic bonding?

A

Metallic bonding is the attraction between the positively charged nuclei of metal atoms and the sea of delocalized valence electrons.

14
Q

What properties of metals are dictated by metallic bonding?

A

Metallic bonding gives metals their ability to conduct heat and electricity, malleability, ductility, and high melting points.

15
Q

What is the bond angle of a water molecule (H2O)?

A

The bond angle of a water molecule is 104.5°.

16
Q

What is the shape and bond angle of an ammonia (NH3) molecule?

A

Ammonia has a trigonal pyramidal shape with a bond angle of 107°.

17
Q

What is the shape and bond angle of a carbon dioxide (CO2) molecule?

A

Carbon dioxide has a linear shape with a bond angle of 180°.

18
Q

What type of bonding is found in NaCl?

A

NaCl has ionic bonding.

19
Q

True or False: Covalent compounds conduct electricity in the molten state.

A

False. Covalent compounds generally do not conduct electricity.

20
Q

What is the electronegativity difference required for a bond to be considered ionic?

A

The electronegativity difference for ionic bonding is equal to or greater than 0.7.

21
Q

What is the electronegativity difference in homonuclear molecules?

A

The electronegativity difference in homonuclear molecules is zero.

22
Q

Why are there more compounds than elements?

A

Atoms of most elements are not stable when isolated and thus combine with other atoms to achieve stability, forming more compounds.

23
Q

How many lone pairs of electrons are present on the nitrogen atom in an NH3 molecule after bonding?

A

There is one lone pair of electrons on the nitrogen atom in an NH3 molecule.

24
Q

What types of bonding are found in ammonium chloride (NH4Cl)?

A

Ammonium chloride contains covalent bonds, dative bonds, and ionic bonds.

25
Q

What are the three-dimensional shapes and bond angles of CH4 and CO2 molecules?

A

CH4 is tetrahedral with a bond angle of 109.5°, and CO2 is linear with a bond angle of 180°.

26
Q

What determines the difference in the melting point of metals?

A

The difference in the melting point of metals is due to the difference in the number of valence electrons and the strength of the metallic bonds.