Acids, Bases & Salts Flashcards

1
Q

Q: What are the general characteristics of acids?

A

A: Acids have a sour taste, turn blue litmus paper red, and produce H₃O⁺ (hydronium) ions in aqueous solutions. They are proton donors.

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2
Q

What are the general characteristics of bases?

A

Bases have a bitter taste, slippery feel, turn red litmus paper blue, and produce OH⁻ (hydroxide) ions in aqueous solutions. They are proton acceptors.

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3
Q

What are the general characteristics of salts?

A

Salts are ionic compounds formed from the neutralization reaction between an acid and a base. They consist of a cation from the base and an anion from the acid.

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4
Q

What is an acid-base indicator?

A

An acid-base indicator is a substance that changes color depending on the pH of the solution, such as litmus, phenolphthalein, and methyl orange.

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5
Q

What is the basicity of an acid?

A

The basicity of an acid refers to the number of hydrogen ions (H⁺) that can be donated per molecule of the acid. For example, HCl has a basicity of 1, H₂SO₄ has a basicity of 2.

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6
Q

What are normal, acidic, basic, and double salts?

A

Normal salts are fully neutralized acids, acidic salts contain replaceable hydrogen ions, basic salts contain replaceable hydroxide ions, and double salts contain two different cations or anions, such as alums.

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7
Q

What are examples of naturally occurring organic acids?

A

Ethanoic acid (vinegar), citric acid (citrus fruits), and tartaric acid (grapes) are examples of naturally occurring organic acids.

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8
Q

How are salts prepared?

A

Salts can be prepared by neutralization (acid + base), precipitation (mixing two solutions to form an insoluble salt), and the action of acids on metals.

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9
Q

What is the difference between strong and weak acids?

A

Strong acids fully dissociate in water, producing a high concentration of ions, while weak acids partially dissociate, producing fewer ions.

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10
Q

How does the conductance of molar solutions relate to the strength of acids and bases?

A

The conductance of a solution increases with the number of ions present; hence, strong acids and bases have higher conductance than weak ones.

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11
Q

What is pH?

A

pH is a measure of the acidity or alkalinity of a solution, calculated as the negative logarithm of the hydrogen ion concentration: pH = -log[H⁺].

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12
Q

What is pOH?

A

pOH is a measure of the hydroxide ion concentration in a solution, calculated as the negative logarithm of the hydroxide ion concentration: pOH = -log[OH⁻].

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13
Q

How are pH and pOH related?

A

pH + pOH = 14 in aqueous solutions at 25°C.

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14
Q

How do you calculate pH from H⁺ concentration?

A

pH = -log[H⁺], where [H⁺] is the concentration of hydrogen ions in moles per liter.

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15
Q

How do you calculate pOH from OH⁻ concentration?

A

pOH = -log[OH⁻], where [OH⁻] is the concentration of hydroxide ions in moles per liter.

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16
Q

What is an acid-base titration?

A

Acid-base titration is a method to determine the concentration of an acid or base by neutralizing it with a base or acid of known concentration.

17
Q

What is the role of an acid-base indicator in titration?

A

An acid-base indicator is used to signal the end point of the titration by changing color when the pH of the solution changes.

18
Q

What is a titration curve?

A

A titration curve is a graph of pH against the volume of titrant added, showing the pH change during a titration and the equivalence point where neutralization occurs.

19
Q

What is salt hydrolysis?

A

Salt hydrolysis is the reaction of a salt with water to form an acidic, basic, or neutral solution depending on the nature of the salt.

20
Q

Give an example of a salt that undergoes acidic hydrolysis.

A

Ammonium chloride (NH₄Cl) undergoes acidic hydrolysis, producing an acidic solution.

21
Q

Give an example of a salt that undergoes basic hydrolysis.

A

Sodium carbonate (Na₂CO₃) undergoes basic hydrolysis, producing a basic solution.

22
Q

What is the hydrolysis equation for sodium acetate (CH₃COONa)?

A

CH₃COONa + H₂O → CH₃COOH + NaOH (produces a basic solution).

23
Q

What is the hydrolysis equation for aluminum chloride (AlCl₃)?

A

AlCl₃ + 3H₂O → Al(OH)₃ + 3HCl (produces an acidic solution).