CHEM IMF CONCEPTS LIQUID Flashcards
explain kinetic molecular theory
offers a description about the microscopic properties of atom or molecules that lead to macroscopic properties changes such as in pressure, volume, and temperature. Application of this would explain why matter exist in different phases (s,l,g), and how to move phases from one to the next
abstractions and generalizations of kinetic molecular theory
- all matter are made up of particles
- all particles have energy, but varies depending on the temperature of the matter
- the temperature is the measure of the average kinetic energy of the substance
- a change in phase occurs if there is a change in energy of the particles
- there are spaces in between molecules
- there are attractive forces between atom/molecules of matter, and it gets stronger when they are closer
- atoms, molecules, ion particles differ in nature depending on its phase of matter
relation of imf to temperature
the stronger the imf the higher the temperature change needed to break the bond in from one phase to the next
these forces of attraction result from temporary dipole moments induced in ordinarily nonpolar molecules
dispersion force
The extent to which a dipole moment can be induced in a molecule
polarisability
relationship of the electron to its polarizability
the more amount of electrons, and the more diffused the electron cloud the more polarizable a particle is
intermolecular forces that are attractive forces between polar molecules
Dipole-Dipole
the relationship of dipole moment to the attractive force
the larger the dipole moment the more stronger the attractive force are
is a special type of dipole-dipole interaction between the hydrogen atom in a polar bond of an electronegative O, N, or F atom
hydrogen bond
explain why surface tension is an intermolecular force
Molecules in liquid state experience strong intermolecular attractive
forces. When those forces are between like molecules, they are referred to as cohesive forces. the molecules of a water droplet are held together by cohesive
forces, and the especially strong cohesive forces at the surface to form surface
tension
generalization and abstraction of properties of liquid
- surface tension, viscosity and capillary action are properties of water that depends on the intermolecular interactions for their behavior
- surface tension is a measure of the elastic force on the surface of a liquid, it is the force that is required to stretch or move the surface of a liquid by a unit area.
- molecules in a liquid are pulled in all directions
- capillary action is the tendency of the water to rise in narrow tubes or be drawn in small openings it is the result of the intermolecular attraction between the water and solid material around it.
- there are two types of forces involved in capillary action (cohesion, adhesion)
- viscosity is the measure of the liquid’s resistance to flow
relate the amount of gas to the vapor pressure
the larger the amount of gas particles the higher the vapor pressure
the pressure exerted by a gas in equilibrium to the liquid in a closed container in a given temperature
vapor pressure of the liquid
relate the temperature to the vapor pressure
the higher the temperature the higher the vapor pressure
is is the energy required to vaporize 1mol of liquid in a given temperature
molar heat of vaporization