Cheat Sheet Flashcards
What happens when a catalyst reduces the Activation Energy?
There is an increase in the rate of the reaction
What is the equation to determine the number of electrons transferred?
it = nF
i = current t = time (s) n = mole of e F = Faradays or 10e5
What is the equation of the emf of a cell?
E˚cell = E˚reduction + E˚oxidation
What is the equation of Gibbs Free Energy?
∆G = -nFEcell ∆G = -RTlnKeq
What are the units for 0 order?
Ms-1
What are the units for 1 order?
s-1
What are the units for 2 order?
M-1s-1
What is the equation for 0 order?
[A]˚ / 2k
What is the equation for 1 order?
0.693 / k
What is the equation for 2 order?
1 / K [A]˚
State functions depend on
Initial and final states
What is the equation for internal energy?
q (heat) + work
What is the equation for heat transferred?
q = mc∆t
What is Gibbs Free Energy regarding spontaneity?
∆G = ∆H - T∆S
What is ∆H?
Enthalpy
What is ∆S?
Entropy
What is ∆G?
Free energy
What is the equation of bond dissociation?
∆H broken - ∆H formed
n = 1 is what series?
Lyman
n = 2 is what series?
Balmer
n = 3 is what series?
Pascher
The max electrons that can be found are
2n^2
What is the equation used to determine the energy of a shell?
(n+1)
What does Pauli state?
No 2 electrons can have the same quantum numbers
What does Aufbau state?
The lowest shells are filled first
What does Hund state?
Unpaired electrons first
l is what number?
0 to (n-1)
m is what number?
+l to -l
What is the trend of electronegativity and ionization?
Increases left to right, down to up
What is the trend of the atomic radius?
Increases right to left, up to down
A period goes
Left to right
A row goes
Up to down
Solubility depends on
- Temperature of solution
- Solvent
- Pressure
The solubility of liquids and solids increases with
Increasing temperature
The solubility of gas increases with
Decreasing temperature
What are soluble salts?
- Group 1A
- NH4+
- Halogens
- SO42-
Halogens are insoluble salts when in contact with
- Ag
- Pb2+
- Hg2+
SO42- is an insoluble salt when in contact with
- Ca2+
- Sr2+
- Ba2+
- Pb2+
What are insoluble salts?
- Metal Oxides
- Hydroxides
- CO32-
- PO43-
- S2-
- SO32-
Metal oxides and hydroxides are soluble when in contact with
- Alkali metals
- CaO
- SrO
- BaO
Describe Galvanic cells
- -∆G
- Spontaneous
- Salt bridges
How is the electron flow in cells?
Goes from anode to cathode
Describe E cells
- ∆G
- non-spontaneous