Ch 25 Flashcards

1
Q

Who published the first version of his periodic table, in which elements were ordered via atomic weight?

A

Dmitri Mendeleev

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2
Q

Henry Moseley organized elements based on

A

Atomic number

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3
Q

The periodic law states that

A

Chemical properties of the elements depend on their atomic number

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4
Q

There are seven periods (rows), each representing

A

The principal quantum numbers n = 1 to n = 7

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5
Q

Groups (columns) represent elements that have the same

A

Electronic configuration in their valence shell

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6
Q

The A elements are the

A

Representative elements

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7
Q

Representative elements have what as their outermost orbitals

A

Sublevels s and p

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8
Q

The B elements are non representative and fill orbitals

A

S, d, and maybe f

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9
Q

Transition elements have partly filled

A

D sublevels

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10
Q

Partly filled f levels are found in

A

Lanthanide and actinide series

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11
Q

From left to right across a period (row), the electrons experience

A

Nuclear attraction, becoming closer to the nucleus

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12
Q

What is the effective nuclear charge?

A

Net positive charge of the nucleus felt on electron

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13
Q

Down a given column, the outermost electrons become

A

Less tightly bound to the nucleus

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14
Q

The number of filled principal energy levels change how as you go downwards a group?

A

Increases

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15
Q

Zeff (effective nuclear charge) is at a maximum for elements

A

In the top-right of the table

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16
Q

Zeff (effective nuclear charge) is at a minimum for elements

A

In the bottom-left

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17
Q

Atomic radius increases

A

Right to left, and from up to down

18
Q

The atoms with the largest radii will be located

A

Bottom of the groups and towards the left of the table

19
Q

Something that affects the size of an electron will also

A

Change radius of an atom

20
Q

The addition of protons increases from left to right across a period, leading to an increase in

A

Zeff (effective nuclear charge)

21
Q

Valence electrons in higher energy shells will feel less pull become

A

Zeff becomes smaller with distance

22
Q

What will be smaller, cations or anions?

23
Q

What is Ionization energy?

A

Energy required to remove an electron from a gaseous atom or ion

24
Q

Removing an electron requires an input of energy, meaning it is

A

Endothermic

25
What it the first ionization energy?
Energy required to remove one valence electron from the parent atom
26
What is the second ionization energy?
Energy needed to remove a second valence electron
27
Ionization energy increases from
Left to right across a period, and going up a group
28
Why do group 1a elements have low ionization energies?
The loss of an electron results in the formation of a stable, noble-gas configuration
29
What is the energy change that occurs when an electron is added to a gaseous atom, representing the ease by which atom can accept the electron?
Electron affinity
30
How is electron affinity when Zeff is high
Electron affinity is great
31
A negative electron affinity represents
Energy release
32
Why do Group VIIA elements, or halogens, have high electron affinities?
The addition of an electron results in a completely filled shell
33
What is the measure of the attraction an atom has for electrons in a chemical bond
Electronegativity
34
The greater an atom's electronegativity, the greater its
Attraction for bonding electrons
35
The most common electronegativity scale is the
Pauling electronegativity scale, ranging from 0.7 to 4.0
36
Electronegativities are related to
Effective nuclear charge
37
Electronegativity increases from
Left to right, and down to up
38
What are the three categories of elements?
Metals, nonmetals, and semimetals
39
Metals have properties like:
- Large atomic radius - Low ionization energy - Low electronegativity - Malleable
40
What is the ability to be drawn into wires called
Ductility