Ch 26 Flashcards

1
Q

Intramolecular bonds hold

A

Atoms together as molecules

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2
Q

Intramolecular bonds include

A

Covalent and ionic bonds

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3
Q

Lithium bonds to form how many valence electrons

A

Two

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4
Q

Beryllium bonds to form how many valence electrons

A

Four

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5
Q

Boron bonds to form how many valence electrons

A

Six

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6
Q

Elements beyond the second row can

A

Expand octets to include more than eight electrons

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7
Q

Ionic compounds form crystal lattices consisting of

A

Arrays of positive and negative ions

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8
Q

Ionic compounds have high melting and boiling points due to

A

Strong electrostatic forces between the ions

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9
Q

Ions can conduct electricity in what state?

A

Liquid / aqueous

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10
Q

Covalent bonds have low melting points and can’t

A

Conduct electricity in the liquid or aqueous states

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11
Q

What features characterize covalent bonds?

A

Bond length and bond energy

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12
Q

What is bond order?

A

The number of shared electron pairs between two atoms

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13
Q

What is the average distance between the two nuclei of atoms in a bond

A

Bond length

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14
Q

A triple bond is shorter than

A

Double bond

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15
Q

A double bond is shorter than

A

Single bond

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16
Q

Bond energy is the energy

A

Required to separate two bonded atoms

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17
Q

The strength of a bond (and bond energy) increases as the

A

Number of shared electron pairs increases

18
Q

H has how many valence electrons

19
Q

C has how many valence electrons

20
Q

N has how many valences electrons

21
Q

What atoms usually are the end electrons?

A

H, F, Cl, Br, I

22
Q

What is the equation for formal charge?

A

V - (number of dots + number of sticks)

23
Q

Formal charges are used to

A

Assess stability of particular resonance structure

24
Q

A stable Lewis structure consists of

A

Negative charges on most electronegative atoms

25
Atoms found in or beyond the third period can have
More than eight valence electrons
26
Atoms found in or beyond the third period can be assigned
More than four bonds
27
The nature of a covalent bond depends on
The relative electronegativities of atoms sharing electron pairs
28
Nonpolar covalent bonding occurs between
Same electronegativities
29
What is a Lewis Acid?
Compound that can accept an electron pair
30
What is a Lewis Base?
Compound that can donate an electron pair
31
Tetrahedral structures are usually
Nonpolar
32
Angular structures are usually
Polar
33
l describes what within n shells
The orbitals
34
S orbitals are
Spherically symmetric
35
P orbitals have what shapes
Dumbbell
36
Bonding orbitals are formed when
Two atomic orbitals are in phase
37
Antibonding orbitals are formed when
Two atomic orbitals are not in phase
38
What bonds are formed when two orbitals of different atoms overlap head-to-head
Sigma bonds
39
What bonds are formed when two p parallel orbitals interact
Pi bonds
40
``` Rate strength of: Dipole-ion Dipole-dipole Hydrogen Bonds London Forces ```
Dipole-ion > HB > dipole-diple > London Forces