Chapter 8: Gas phase Flashcards
pressure equivalents
1 atm = 760 mmHg = 760 torr = 101.325 kPa
what is standard temp and pressure
273 K and 1 atm
what is the avogadros principle
special gas for ideal gas where temp and pressure is constant; shows relationship between moles and volume
what is boyles law
temp and moles constant; shows inverse relationship between pressure and volume
what is charles law
pressure and moles constants; shows direct relationship between temp and volume
what is gay lussacs law
volume and moles constant; show direct relationship between temp and pressure
what is the combined gas law
shows inverse relationship between pressure and volume along with direct relationship between pressure and volume with temp
what is daltons law of partial pressure
states that individual gas components of a mixture of gases with exert individual pressures in proportion to their mole fractions; total pressure is equal to sum of partial
what is henrys law
states that the amount of gas dissolved in solution is directly proportional to partial pressure of that gas at the surface of solution
what are the assumptions in kinetic molecular theory
1) gas particles have negligible vol
2) no attraction or repulsion
3) random collisions w each other + walls of container
4) collisions are elastic
5) average kinetic energy is directly proportional to temp
what is grahams law
gases with lower molar mass will diffuse/effuse faster than gases with higher molar mass at the same temp
how do real gases deviate in terms of volume at high pressure, low volume, and low temp
real gases will occupy LESS volume than predicted because of intermolecular attractions
how do real gases deviate in volume extremely high pressure, low volume, and low temp
will occupy more volume than predicted because the particles occupy physical space
what is Van der Waals equation of state for
used to correct the ideal gas law for intermolecular attractions and molecular volume
equation for ideal gas law
PV = nRT