Chapter 8: Gas phase Flashcards

1
Q

pressure equivalents

A

1 atm = 760 mmHg = 760 torr = 101.325 kPa

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2
Q

what is standard temp and pressure

A

273 K and 1 atm

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3
Q

what is the avogadros principle

A

special gas for ideal gas where temp and pressure is constant; shows relationship between moles and volume

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4
Q

what is boyles law

A

temp and moles constant; shows inverse relationship between pressure and volume

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5
Q

what is charles law

A

pressure and moles constants; shows direct relationship between temp and volume

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6
Q

what is gay lussacs law

A

volume and moles constant; show direct relationship between temp and pressure

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7
Q

what is the combined gas law

A

shows inverse relationship between pressure and volume along with direct relationship between pressure and volume with temp

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8
Q

what is daltons law of partial pressure

A

states that individual gas components of a mixture of gases with exert individual pressures in proportion to their mole fractions; total pressure is equal to sum of partial

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9
Q

what is henrys law

A

states that the amount of gas dissolved in solution is directly proportional to partial pressure of that gas at the surface of solution

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10
Q

what are the assumptions in kinetic molecular theory

A

1) gas particles have negligible vol
2) no attraction or repulsion
3) random collisions w each other + walls of container
4) collisions are elastic
5) average kinetic energy is directly proportional to temp

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11
Q

what is grahams law

A

gases with lower molar mass will diffuse/effuse faster than gases with higher molar mass at the same temp

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12
Q

how do real gases deviate in terms of volume at high pressure, low volume, and low temp

A

real gases will occupy LESS volume than predicted because of intermolecular attractions

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13
Q

how do real gases deviate in volume extremely high pressure, low volume, and low temp

A

will occupy more volume than predicted because the particles occupy physical space

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14
Q

what is Van der Waals equation of state for

A

used to correct the ideal gas law for intermolecular attractions and molecular volume

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15
Q

equation for ideal gas law

A

PV = nRT

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16
Q

equation for density of a gas

A

p = m/V = PM/RT

17
Q

equation for combined gas law

A

P1V1/T1 = P2V2/T2

18
Q

equation for avogadros principle

A

n1/V1 = n2/V2

19
Q

equation for boyles law

A

P1V1 = P2V2

20
Q

equation for charles law

A

V1/T1 = V2/T2

21
Q

equation for Gay Lussac law

A

P1/T1 = P2/T2

22
Q

Kinetic energy eqaution

A

KE = 1/2 mV^2 = 3/2KbT
Kb =1.38 x 10^-23 J/K

23
Q

root mean square speed

A

rms = Square root ( 3RT/M)

24
Q

grahams law equation

A

r1/r2 = square root (M2/M1)
r = diffusion rates
M = molar mass

25
Q

what is equation for mole fraction (X)

A

Moles gas A / total moles of gases

26
Q

what is equation for henrys law

A

[A] = Kh x Pa or Kh = [A1]/P1
Kh = henrys constant

27
Q

what is equation for partial pressure

A

Pa = X * Ptotal

28
Q

what is the ideal gas constant

A

0.0821 L*atm/mol * K