Chapter 5,11, 24: Chem Definitions Flashcards
Octet Rule
When bonding occurs, atoms tend to reach an arrangement with 8 electrons in the outermost energy level
Ion
A charged atom or group of atoms
Compound
2 or more different elements chemically combined
Ionic bond
The force of attraction between oppositely charged ions in a compound through the transfer of electrons from one atom to another
Transition metal
One that forms at least one ion with a partially filled d sublevel
Molecule
A group of atoms joined together
Valency
The number of atoms of hydrogen or any other monovalent element with which each atom of the element combines
Sigma bond
The head-on overlap of 2 orbitals
Pi bond
The sideways overlap of p orbitals
Electronegative
The relative attraction than an atom in a molecule has for the shared pair of electrons in a covalent bond
Polar covalent bond
A bond with which there is unequal sharing of electrons
eg, HCl
1.8 or more
Ionic bond
1.7 or less
Covalent bond
0.5 - 1.6
Polar covalent bond
0.4 or less
Non-polar
Intramolecular bonding
Bonding that takes place within a molecule
e.g, polar covalent bonding
Intermolecular bonding
Forces of attraction that exists between molecules
e.g, Van der Waals forces
Van der Waals forces
Weak attractive forces between molecules resulting from the formation of temporary dipoles
Dipole-dipole forces
Forces of attraction between the negative pole of one polar molecule and the positive pole of another polar ,molecule
Hydrogen bonds
Particular types of dipole-dipole attractions between molecules in which hydrogen atoms are bounded to nitrogen, oxygen or fluorine
Atomic radius
Half the distance between the nuclei of two atoms of the same element that are joined together by covalent bonds
First ionisation of energy
The minimum energy required to completely remove the most loosely bound electron from a neutral gaseous atom in its ground state
Formula for first ionisation of energy
X(g) —> X+(g) + e-
Second ionisation of energy
The energy required to remove an electron from an ion with one positive charge in the gaseous state