Chapter 3 - Amount of substance Flashcards

1
Q

What is the Avogadro constant?

A

6.02 x 10^23

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2
Q

The equation for the number of moles

A

Mass / Mr

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3
Q

What is the molar mass?

A

The mass of one mole of something

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4
Q

How to work out the number of moles of something?

A

Multiply the number of moles by the Avogadro constant

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5
Q

What is the molar gas volume?

A

The space that one mole of a gas occupies at room temperature and pressure

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6
Q

The equation for the number of moles of a gas

A

Volume (dm3) / 24 dm^3

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7
Q

What is the empirical formula

A

The smallest whole number of atoms of each element in a compound

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8
Q

What is the molecular formula?

A

The actual number of atoms of each element in a compound

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9
Q

Formula of nitrate

A

NO3 -

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10
Q

Formula of carbonate

A

CO3 2-

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11
Q

Formula of sulfate

A

SO4 2-

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12
Q

Formula of hydroxide

A

OH-

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13
Q

Formula of ammonia

A

NH4 +

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14
Q

Formula of zinc

A

Zn 2+

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15
Q

Formula of silver

A

Ag +

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16
Q

What is important to remember about ionic compounds?

A

The charges always balance

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17
Q

What is produced when acids and bases react?

A

Water and a salt

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18
Q

What is the water of crystallisation?

A

The water in an ionic lattice

19
Q

How to work out the water of crystallisation?

A

Use COMMA R (see cards)

20
Q

What is the empirical formula of a compound?

A

The smallest whole number ratio of atoms in a compound

21
Q

What is the molecular formula of a compound?

A

The actual number of atoms of each element in a molecule

22
Q

How to calculate the empirical and molecular formula?

A

Use EMMA and COMMA R

23
Q

What is relative molecular mass?

A

The mass of a molecule compared to the mass of an atom of carbon 12

24
Q

What is the relative formula mass?

A

Compares the mass of a formula unit with the mass of an atom of carbon-12

25
What is the water of crystallisation?
The water molecules that are part of the crystalline structure of a salt
26
Assumptions made when using experimental formula (2)
All of the water has been lost | No further decomposition
27
What is a polyprotic acid?
One which donates more than one proton
28
What is the ideal gas equation?
Pressure x volume = moles x ideal gas constant x temperature
29
What is the ideal gas constant?
8.31 Jmol-1K-1
30
How to go from cm3 to m3?
x10(-6)
31
How to go from dm3 to m3?
x10(-3)
32
How to go from Celsius to Kelvin?
+273
33
How to go from kPa to Pa?
x10(3)
34
What is stoichiometry?
The ratio of the moles of each reacting substance
35
Reasons why maximum theoretical yield is rarely reached (3)
The reaction may not have gone to completion Side reactions may have taken place as well Purifying the product may result in the loss of some of it
36
Equation for percentage yield
(Actual yield/theoretical yield) x 100
37
What is the limiting reagent?
The one that will be used up first and stop the reaction
38
How to find the limiting reagent?
Work out the moles of each reagent and compare with the equation
39
What is atom economy?
The proportion of atoms in the reagents that end up as the products
40
Equation for atom economy
(Mr of desired product / Mr of all products) x100
41
What is a standard solution?
One with a known concentration
42
How would you work out the formula of a hydrated salt?
1) Weigh an empty crucible 2) Add the hydrated salt into it and weigh again 3) Heat the crucible and contents strongly for about 3 minutes 4) After leaving to cool, reweigh the crucible and remaining salt
43
Why aren't experiments to determine the water of crystallisation always accurate?
They assume that all of the water has been lost and that there is no further decomposition after heating
44
What is the ideal gas equation?
pV = nRT