Chapter 14 - Analysis of Organic Compounds by Volumetric Analysis Flashcards
volumetric analysis
used to determine the amount or concentration of a dissolved substance in a solution
burette
used to accurately measure variable volumes (titre)
pipette
used to accurately measure fixed volumes (aliquot)
indicator
used to show when a chemical reaction has reached completion
volumetric flask
used to make up accurate volumes of solution
titre
accurate variable volume delivered from a burette.
calculated by subtracting the initial burette reading from the final
aliquot
accurate fixed volume delivered from a pipette
equivalence point
point in titration when reactants are in exactly correct mole ratio as shown by equation
end point
point when one reactant is in slight excess, causing a significant colour change
indicator
chemical that has two distinctly different colours depending upon the nature of the chemical in excess
concordant
titres that are in close agreement (within 0.10 mL)
standard solution
solution with an accurately known concentration
primary standard
substance used to make a standard solution
titration
process used to determine the concentration of a reactant where one solution is added from a burette to a known volume of another solution
precise
repeated measures of the same quantity give values that are in close agreement
accurate
average of a set of measurements is very close to true or expected value of quantity being measured
mistakes
avoidable errors
systematic errors
produces a constant bias in a measurement that cannot be eliminated by reacting the measurement
random errors
follow no regular pattern
organic acids
organic compound that contains a functional group that can donate one proton.
eg. carboxylic acid
organic bases
organic compound that contains a functional group that can accept one proton.
eg. amine
monoprotic acids
an acid that can donate only one hydrogen ion
polyprotic acids
an acid that can donate more than one hydrogen ion