Chapter 10 - Structure and Nomenclature of Organic Compounds Flashcards

1
Q

organic molecules

A

compounds containing carbon atoms linked to each other, and to other non-metallic atoms by covalent bonds

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2
Q

saturated molecule

A

single bonds only

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3
Q

unsaturated molecule

A

one or more carbon to carbon double or triple bonds

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4
Q

hydrocarbon

A

compound that contains carbon and hydrogen only

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5
Q

molecular formula

A

gives actual number and type of atoms present in molecule

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6
Q

structural formula

A

represents 3D arrangement of atoms in a molecule

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7
Q

semistructural formula

A

condensed formula that summarises structural formula in single line

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8
Q

isomers

A

molecules that contain the same number and type of atoms, arranged in different ways

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9
Q

structural isomers

A

have the same molecular formulas of atoms in a molecule.

chain and positional

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10
Q

chain isomers

A

difference in the branching of the hydrocarbon chain

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11
Q

positional isomers

A

functional group in a different location on the carbon chain

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12
Q

stereoisomers

A

isomer where atoms in 2 molecules are connected in same order, but have different arrangements.
optical and geometric

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13
Q

optical isomers

A

different placement of groups around one atom in a molecule

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14
Q

chiral

A

not superimposable on its mirror image.

no plane of symmetry

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15
Q

chiral centre

A

carbon atom attached to 4 different groups

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16
Q

enantiomers

A

pair of chiral molecules

17
Q

geometric isomers

A

occurs when theres restricted rotation in molecule.
carbon to carbon double bond.
cis and trans

18
Q

cis isomers

A

groups on same side.

longest alkyl group attached to same side of double bond

19
Q

trans isomers

A

groups on opposite sides.

longest alkyl groups attached to opposite sides of double bond

20
Q

homologous series

A

series of organic compounds in which each member of the group differs from the previous member by a -CH2 unit

21
Q

alkanes

A

hydrocarbons with only single bonds.
non-polar.
saturated.
CnH2n+2

22
Q

cyclohexane

A

carbon atoms formed in a ring (cyclic)

23
Q

cyclic molecules

A

molecule that form rings

24
Q

alkenes

A

hydrocarbons that contain a carbon-carbon double bond.
non-polar.
unsaturated.
CnH2n

25
Q

alkynes

A

hydrocarbons that contain carbon-carbon triple bonds.
unsaturated.
CnH2n-n

26
Q

benzene

A

unsaturated cyclic hydrocarbon molecule.
C6H6.
4th electron is delocalised around all carbons

27
Q

functional group

A

atom or group of atoms in organic molecules that largely determines the molecules properties and reactions

28
Q

haloalkanes

A

derived from alkanes, in which a hydrogen atom is replaced with a halogen atom

29
Q

alcohols

A

contain the hydroxyl (-OH) group

30
Q

primary alcohol

A

carbon bonded to the -OH group is only attached to one alkyl group

31
Q

secondary alcohol

A

carbon bonded to the -OH group is also bonded to two alkyl groups

32
Q

tertiary alcohol

A

carbon bonded to the -OH group is also bonded to three alkyl groups

33
Q

primary amines

A

contains the amino (-NH2) functional group

34
Q

aldehydes

A

contains the carbonyl (C=O) group bonded to a hydrogen on one end of the molecule.
recognised by presence of -CHO group at one end on structural formula

35
Q

ketones

A

contains the carbonyl functional group (C=O) within carbon chain

36
Q

carboxylic acid

A

contain the carboxyl group (-COOH).

always located at end of chain

37
Q

amides

A
contains the (-CONH-) group.
always located at end of chain
38
Q

esters

A
contain ester (-COO-) group.
located within chain