Chapter 0g: Solutions Flashcards

1
Q
  • homogeneous mixtures of two or more substances
  • form when there is sufficient attraction between the solute and solvent molecules
A

solutions

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2
Q

two components of solutions

A
  1. solvent
  2. solute
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3
Q

present in larger amount

A

solvent

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4
Q

present in smaller amount

A

solute

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5
Q

Solutes and solvents may be… ?

A
  • liquid
  • gas
  • solid
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6
Q

solutes are mixed with solvents so that they have the same __ __

A

physical state

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7
Q

solutes in a solution cannot be separated by __, but can be separated by __

A
  • filtration
  • evaporation
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8
Q
  • one of the most common solvents in nature
  • polar molecule due to polar O-H bonds
  • molecules form hydrogen bonds
A

water

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9
Q

what type of molecule is water

A

polar molecule (O-H bonds)

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10
Q

How are solutions formed

A

solute-solvent interactions are large enough to overcome solute-solute interactions and solvent-solvent interactions

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11
Q

what dissolves what

A

like dissolves like
(polar - polar)
(nonpolar - nonpolar)

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12
Q

ex. of nonpolar molecules

A
  1. iodine
  2. oil
  3. grease
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13
Q

play an important role in maintaining proper function of cells and organs

A

electrolytes

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14
Q

Types of electrolytes

A
  1. strong electrolytes
  2. weak electrolytes
  3. nonelectrolytes
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15
Q
  • dissociate 100% in water
  • produce positive and negative ions
  • form solutions that conduct an electric current strong enough to light a bulb
A

strong electrolytes

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16
Q
  • dissociates only slightly in water
  • forms a solution with a few ions and mostly undissociated molecules
A

weak electrolytes

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17
Q
  • dissolve as molecules in water
  • do not produce ions in water
  • do not conduct an electric current
A

nonelectrolytes

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18
Q

Ex. of strong electrolyte formula

A

NaCl(s) –> Na+(aq) + Cl-(aq)

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19
Q

Ex. of weak electrolyte formula

A

HF(aq) <–> H+(aq) + F-(aq)

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20
Q

Ex. of nonelectrolyte formula

A

C12H22O11(s) –> C12H22O11(aq)

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21
Q

Examples of strong electrolytes

A
  • ionic compounds
  • acids such as HCl, HBr, HI, HNO3, HClO4, H2SO4
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22
Q

Examples of weak electrolytes

A
  • HF
  • H2O
  • NH3
  • HC2H3O2 (acetic acid)
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23
Q

Examples of nonelectrolytes

A

carbon compounds
- methanol (CH3OH)
- ethanol (C2H5OH)
- sucrose (C12H22O11)
- urea (CH4N2O)

24
Q

amount of an electrolyte or an ion that provides 1 mole of electrical charge

A

equivalent (Eq)

25
In solution, the charge of positive and negative ions are always __
balanced
26
electrolytes in intravenous fluids are expressed in __
mEq/L
27
maximum amount of solute that dissolves in a specific amount of solvent
solubility
28
how is solubility expressed
g of solute / 100 g water
29
Two types of solution
1. unsaturated solution 2. saturated solution
30
- contain less than the maximum amount of solute - can dissolve more solute
unsaturated solutions
31
- contain the maximum amount of solute that can dissolve - have undissolved solute at the bottom of the container - contain solute that dissolves as well as solute that recrystallizes in an equilibrium process
saturated solutions
32
saturated solution formula
solute + solvent --> (solute dissolves) (solute recrystallizes) <-- saturated solution
33
where does solubility depend
temperature
34
solubility of solids: temperature increases
more soluble
35
solubility of gases: temperature increases
less soluble
36
- states that the solubility of a gas in a liquid is directly related to the pressure of that gas above the liquid - at higher pressures, more gas molecules dissolve in the liquid
Henry's law
37
when the pressure of a gas above a solution decreases, what happens to the solubility of that gas in the solution
also decreases
38
How are ionic compounds soluble in water
if they contain soluble cation or anion
39
Soluble in Water: Positive ions
1. Li+ 2. Na+ 3. K+ 4. Rb+ 5. Cs+ 6. NH4+
40
Soluble in Water: Negative ions
1. NO3 - 2. C2H3O2 - 3. Cl - 4. Br - 5. I - 6. SO4 2-
41
Cl-, Br-, I- are insoluble when combined with...?
1. Ag+ 2. Pb 2+ 3. Hg2 2+
42
SO4 2- is insoluble when combined with...?
1. Ba 2+ 2. Pb 2+ 3. Ca 2+ 4. Sr 2+ 5. Hg2 2+
43
Ionic compounds that do not contai at least one of the soluble ions are usually __
insoluble
44
used to enhance x-rays
BaSO4
45
mass percent (m/m)
g/g
46
volume percent (v/v)
mL/mL
47
mass/volume percent (m/v)
g/mL
48
When writing a net ionic equation, what is removed
spectator ions
49
ions which do not participate in chemical reactions and present the same on both sides of the reactions
spectator ions
50
a solvent, usually water, is added to a solution, which increases its volume and decreases the concentration of the solution
dilution
51
what is added in a dilution
water
52
what is the same in the initial and diluted solution
moles of solute
53
equation that relate concentration and volumes
C1V1 = C2V2
54
concentration, C, may be __ or __
- percent concentration - molarity
55
Freezing point depression of water
1.86°C kg/mol
56
Boiling point elevation of water
0.515°C kg/mol