ch 9 Flashcards

1
Q

what are the sulfur gasses

A

CS2

COS

dimethyl sulfide

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2
Q

what are the halogen gasses

A

methyl chloride or iodide

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3
Q

what are the nitrogen gasses

A

N2O

alkyl nitrates

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4
Q

what are the carbon gasses

A

CH4

CO2

CO

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5
Q

what gasses impact the climate

A

greenhouse gasses like CH4, DMS

increase cloudiness, air quality is affected and the ozone is depleted

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6
Q

what are the types of gasses producedby photosynth that are net influxed into the ocean

A

sulfur gasses
carbon gasses
nitrogen gasses
halogen gasses

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7
Q

what is the water. a significan sink for

A

O3

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8
Q

what is the ocean a sink for

A

O3
persistent organic pollutatns like PCB, DDT, PFAAs
CFCs
SO2

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9
Q

what gasses have fluxes that are variable in space and time

A

H2S
NH3
CO2
Hg

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10
Q

what is the name for aerosols

A

air solutions

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11
Q

what do aerosols affect

A

visibility
air quality
climate

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12
Q

lifetime of aerosols

A

short lives, deposit to the surface in few horur to a couple of weeks

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13
Q

aerosols emitted from the ocean are known as

A

sea spray
marine aerosols

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14
Q

what is sea spray/ marine aerosols composed of

A

sea salts and oganics

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15
Q

what is the major marine aerosol emission pathwat

A

bubble bursting

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16
Q

how are larger aerosols emitted

A

by jet drop formatino

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17
Q

what are larger aerosols rich in

A

sea salt- the majority

18
Q

what are smlaler aerosols produced by

A

film drop formation

19
Q

what are smaller aerosols rich in

A

organics similar to those that make up the SML

soluble and insoluble kind

20
Q

what is the change in organics observed in tthe winte

A

less organics because

21
Q

what do marine aerosols impact

A

the climate

22
Q

how do marine aerosols impact the climate directly

A

absorbing or scattering incoming radiation to warm or cool the surface of the earth respectively

23
Q

how do marine aerosols iimpact the climate indirecrtly

A

they act as cloud condensation nuclei CCN

leading to cloud formaiton and reflection of lightand the cooling of the surfcae of the earth

24
Q

the films in the thin film model are

A

stagnant and dominated by diffusion processes

25
diffusion _ the gradient
weakens
26
what is the rate limiting step for most gasses
diffusion through the seawater film is the slower rate limiting step
27
does the film thickeness depend or not depend on the gas
it is not gas dependent
28
what is the net flux described by
ficks law-- proportional to the concentration gradient
29
what does the net flux depend on
the concentration gradient thickness of the film
30
what is KhPa equal to
NAEC
31
what is Da/Z equal to
piston velocity or transfer velocity
32
what is Da
diffusion coefficient- it is diff for diff gasses and decreases with molecular weight
33
what changes the diffusion coefficient and flux
increase with an increase in temp
34
the fact that diff gasses have diff D indicates that within the film.
molecular diffusion domenates over turbulent diffusion bc turbulent diffusion moves entire parcels of water with all dissolved gasses in them
35
how does the thin film exist in real life
as a surface microlayer
36
what is high inthe sea surface microlayer
bacteria metals DOM
37
how does the microlayer affect waves
it dampens the affect of wind on waves bc wind slides over water preventing drag and doesnt build up waves
38
what does the thickness of the film depend on
wind speed wind generated turbulence erases the film and the bubble transport dominates
39
what is the typical thickness of the film
10-60 um
40