ch 5 Flashcards
what is the size of dissolved material
less than 1 nm
why is colloid study important in chem oceanography
things we think are dissolved may be particulate- have different processes dictating their cycling
hydrophobic substances in or on colloids
where are colloids found
in dispersion medium- larger than 1 nm- diff from dissolves
what differentiates dissolevd matter from colloid
colloid doesnt pass semipereable membrane
elevates boiling point
lowers freezing point
no effect on osmotic pressure
what is the similarity between dissolved and colloidal matter
doesnt settle
homogenous, clear, doesnt settle
solution
doesnt settle, not clear
colloiids
settles, heterogenous, cloudy
suspension
example of solution
saltwater
example of colloid
virus in seawater or milk
example of suspension
mud
larger versus smaller bubbles and stokes law
smaller bubbles can collapse, higher SA to volume ratio- rise slower - negative answer to stokes law- lose a lot of air as they rise because they rise slowly
surface tension in small versus large bubbles
higher in smaller bubbles
cyanobacteria and gasses- stokes law
they produce N2- helps them rise and be clsoer to light for photosynthesis- they have acess to N2 to fix it
what is marine snow
decomposing organic matter
their density is very slighly higher than water byut sometimes can get stuck in the therocline since in the thermocline the density increases to equal the marine snow
how is organic carbon shipped into the deep ocean
larvacean mucus houses and fecal pellets
what is stokes equation exact for
spherical and smooth paritcles and small slowly sinking particles that are not much denser than water
less than 100 um
why does stokes law not apply to fast sinking particles
because fast sinking large particles with lwoer SA to volume ratio vause TURBULENCE due to friction and drag of water- changes u in denominator of stokes equation
stokes overestimates speed for fast praticles due to drag
small sphere falling under action of gravity in viscous medium reaches a constant sinking velocity
stokes law
how do we operationally define suspended versus settingg mattter
caught in sediment trap or caught in water sampler
what are the filters we use to operationally define dissolved or particulate matter
first membrane filter 0.45 um then glass fibre filer
what are the issues with using filters
there are 3 nominal pore sizes
different manufacturers define the sizes differently - different methods to calcuate nominal pore size
they state the absolute retention siez- some can be squeezed through
biology, why do we need distinction bw dissolved and particulate matter
distinguish bw living and recently living
vs
material exuded or excreted or broken down
chem, why do we need distinction bw dissolved and particulate matter
distinguish bw suspended solids/ micelles aggregates
vs
single molecules, ions, dimers, oligomers