Ch - 8 (Rates of Reaction) Flashcards

1
Q

What are the factors that affect the rate of reaction?

A
  • Concentration of reactant in solution
  • Pressure of reacting gases.
  • Temperature
  • Surface area of solid reactant
  • Use of catalyst
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2
Q

What is one use of the rate?

A

Economic Interest

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3
Q

On a graph, of increased concentration or pressure, how will u determine the line with more concentration?

A
  1. Steeper line - Higher concentration
  2. Less steeper line - Less concentration.
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4
Q

On a graph, of surface area, how will u determine the line with more surface area?

A
  1. Steeper line - More surface area (powder)
  2. less steeper line - Less surface area (lumps)
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5
Q

On a graph, on temp, how will u determine the line with more temp?

A
  1. Steeper Line - Higher temp.
  2. Less steeper line - Lower temp.
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6
Q

What is a catalyst?

A
  • Speeds up the rate of reaction, without being altered or consumed itself.
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7
Q

What is one important thing to note about a reaction?

A

Mass of reactant = Mass of product

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8
Q

On a graph, on catalyst, how will u determine the line with a catalyst?

A
  1. Steeper line - with a catalyst
  2. less steeper line - without a catalyst
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9
Q

What does the collision theory state?

A
  • the particles must collide with each other
  • collision must have sufficient energy to cause reaction
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10
Q

What is activation energy?

A

The minimum energy that colliding particles must have.

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11
Q

What is it called if a collision occurs?

A

Successful collisions.

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12
Q

What does the no. of successful collisions depend on?

A
  1. No. of particles per unit volume
  2. Frequency of collisions
  3. Kinetic energy of particles
  4. Activation energy
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13
Q

How does temp affect the rate of reaction?

A

Increasing the temp will increase the rate of reaction.

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14
Q

Explain according to particle theory the effect of temp.

A
  • More frequent collisions
  • Higher proportion of particles have energy greater than the activation energy.
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15
Q

What is the rule of thumb for aqueous and gaseous systems?

A
  • For every 10°C increase in temp, the rate of reaction approx doubles.
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16
Q

How does concentration affect the rate of reaction?

A

Increasing the concentration of the solution will increase the rate of reaction.

17
Q

Explain according to particle theory the effect of concentration.

A
  • More reactant particles in a given volume.
  • ## More frequent and successful collisions per second.
18
Q

What about the gaseous state reaction?

A
  • Increases the pressure has same effect as the no. of particles occupy in small space
    -This increases concentration
19
Q

What will happen if we double the no. of collisions?

A

Double the no. of collisions per sec

20
Q

What can we conclude from the no. Of collisions ?

A

No. of collisions is proportional to the no. of particles present.

21
Q

How does surface area affect the rate of reaction?

A

Increasing the surface area of the solid will increase the rate of reaction.

22
Q

Explain according to particle theory the effect of surface area.

A
  • More surface area of particles is exposed
  • Producing higher no. Of collisions per sec
23
Q

What will happen if we double the surface area?

A

Double the no. of collisions per sec

24
Q

What is a catalyst?

A

Catalyst is a substance which speeds up the rate of reaction without being altered or consumed in the reaction.

25
Q

What principle do all catalysts work on?

A
  • Providing a different pathway for the reaction to occur that has lower activation energy.
26
Q

What is an example of a catalyst?

A
  • Iron
  • Used to catalyse the Haber Process for production of Ammonia
27
Q

What are iron beads used for?

A

Surface area available for catalysis

28
Q

What are enzymes?

A

Enzymes are biological catalysts that work best at specific temp. & pH

29
Q

How much of the catalyst is required for a reaction to take place?

A

Small amounts

30
Q

What shud u mention when answering questions on the effect of concentration on rate of reaction?

A

More particles per unit volume

31
Q

How do we measure the rate of reaction?

A
  • How quickly reactants are used up
  • How quickly products are formed.
32
Q

What are the most common techniques used to measure rate of reaction?

A
  • Measuring mass loss on balance
  • Measuring volume of gas produced.
  • measuring colour change at the end of reaction.