Ch - 7 (Chemical Energetics) Flashcards

1
Q

When do exothermic and endothermic reactions take place?

A

Chemical bonding

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2
Q

What does chemical bonding involve?

A

The transfer of thermal energy in or out.

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3
Q

What are the 2 key terms involved in the transfer of thermal energy?

A
  • System (What happens in the chemical reaction)
  • Surroundings (anything other than the chemicals reacting)
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4
Q

What happens in an exothermic reaction?

A
  • Thermal energy is transferred from the system to the surroundings.
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5
Q

What happens to the surrounding temp. in an exothermic reaction?

A

Temp. increases

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6
Q

Why is the energy change in an exothermic reaction negative?

A
  • The energy is transferred from the chemical energy store of the chemical system to the surroundings
  • Energy of the system falls.
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7
Q

What are examples of an exothermic reaction?

A
  • Combustion
  • Oxidation
  • Neutralisation reactions.
  • Handwarmers
  • Self-heating cans of food n drinks
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8
Q

What happens in an endothermic reaction?

A

Thermal energy is transferred from the surroundings into the systems

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9
Q

why is the energy change in an endothermic reaction positive?

A

This energy is transferred to the chemical energy story of the chemical systems

  • Energy of the system increases.
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10
Q

what are examples of endothermic reactions?

A
  • Electrolysis
  • Thermal decomposition reactions
  • Photosynthesis First stages
  • Cold packs
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11
Q

What are reaction pathways diagrams or energy level diagrams?

A

Graphical representation of relative energies of the reactants and products in chemical reactions.

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12
Q

What represents the overall energy change of a reaction?

A

The diff. in height between the energy of reactants and products

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13
Q

What represents the activation energy (Ea)?

A

The initial increase in energy.

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14
Q

Define Ea.

A

Minimum energy that colliding particles must have in order to react.

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15
Q

How can we identify a reaction pathway diagram for an exothermic reaction?

A
  • Energy of the product is lower than the reactants
  • (As thermal energy has been transferred to the surroundings)
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16
Q

How can we identify a reaction pathway diagram for an endothermic reaction?

A
  • The energy of the product is higher than the reactants.
  • (As thermal energy has been taken in from the surroundings.
17
Q

What is an easy way to understand the direction of thermal energy in endo n exothermic reactions?

A

EXothermic - EXits

ENdothermic - ENters

18
Q

What must atoms or particles do to react with each other in a chemical system?

A

come into contact in a collision

19
Q

What factors come into play when analyzing collisions?

A
  • Energy
  • Orientation
  • No. of collisions per sec (Frequency)
20
Q

What is the transfer of thermal energy during a reaction called?

A

Enthalpy change, delta H

21
Q

Which reaction is bond breaking?

A

Endothermic (energy needs to be taken in to break bonds)

22
Q

What reaction Is bond making?

A

Exothermic reaction (Energy is transferred to the surroundings as the new bond is formed)

23
Q

what is it called if more energy is released than absorbed?

A

Exothermic

24
Q

what is it called if more energy is absorbed than released?

A

Endothermic

25
Q

What is the formula for enthalpy change? (delta H)

A

Enthalpy change(^H) = Energy taken in - Energy given out.

26
Q

What is bond energy calculations useful for?

A

used to calculate how much heat is released or absorbed.

27
Q

what is the method to solve bond energy calculations?

A
  1. Write the balanced equation
  2. Draw displayed formula to identify type & no. of bonds (Optional)
  3. Add bond energy in reactants (Energy in)
  4. Add bond energy in products (Energy out)
  5. Calculate enthalpy change.
28
Q

What are physical changes?

A
  • Such as melting or evaporating.
  • Do not produce any new chemical system.
  • Easy to reverse.
29
Q

What are chemical changes?

A
  • New chemical substances are formed.
  • have different properties to reactants
  • cannot be reversed
30
Q

What are signs to identify a new substance is formed in chemical change?

A
  • color change
  • precipitate
  • bubbles of gas being formed