ch 8: energy and enzymes Flashcards

1
Q

1st law of thermodynamics

A

energy is neither created, nor destroyed
- it can be transferred or transformed

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2
Q

2nd law of thermodynamics

A

when energy is converted from one form to another, some of that energy becomes unavailable to do work

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3
Q

why do products have less potential energy than the reactants in biochemical reactions?

A

due to a release of energy during the reaction

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4
Q

what type of energy is released during the hydrolysis of polymers?

A

chemical energy

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5
Q

what helps drive the movement of ions through channels?

A

electrical gradients

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6
Q

what can be released by chemical reactions?

A

heat

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7
Q

what is captured by pigments?

A

light energy

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8
Q

what is used in muscle movements?

A

mechanical energy

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9
Q

metabolism

A

sum of all biochemical reactions in an organism

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10
Q

catabolic reactions

A

break down molecules
- example: hydrolysis

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11
Q

anabolic reactions

A

reactions that build molecules
- example: condensation

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12
Q

exergonic

A

when G is negative —> energy is released
- spontaneous

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13
Q

endergonic

A

when G is positive –> energy is consumed
- nonspontaneous

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14
Q

example of endergonic reaction

A

active transport

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15
Q

example of exergonic reaction

A

diffusion

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16
Q

if a bond is harder to break, why does it have less potential energy?

A

energy gets used up because it takes more energy to break the bond

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17
Q

do nonpolar bonds have high or low potential energy?

A

high

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18
Q

do polar bonds have high or low potential energy?

19
Q

redox reactions

A

oxidation and reduction

20
Q

oxidation

A

loss of electron

21
Q

reduction

A

gain of electron

22
Q

what do redox reactions transfer?

A

electrons alone or along with protons (H+)

23
Q

when NAD gets reduced, it becomes

24
Q

when FAD2+ gets reduced, it becomes

25
what type of reaction is reducing FAD and NAD?
endergonic, non-spontaneous reactions
26
where does ATP hold energy?
phosphate bonds
27
coupling reactions
energy released from an exergonic reaction drives an endergonic reaction
28
what has to happen for FAD and NAD to be reduced?
the reaction has to be coupled with another one
29
what happens when ATP is hydrolyzed?
energy is released
30
is ATP hydrolysis a redox reaction?
no, it is a catabolic reaction because it involves breaking down a molecule not transferring electrons/protons
31
what is the endergonic reaction of the ATP cycle?
a phosphate group gets added to ADP to create ATP and energy is added (ATP synthesis)
32
what is the exergonic reaction of the ATP cycle?
phosphate is removed from ATP to create ADP and energy is released (ATP hydrolysis)
33
exergonic reactions ____ energy
release
34
endergonic reactions ____ energy
require
35
what is ATP hydrolysis coupled to?
endergonic reactions
36
what links endergonic and exergonic pathways?
ATP hydrolysis + condensation
37
what do enzymes contain to help biochemical reactions?
binding sites for coupled reactions
38
do enzymes reduce or increase the activation energy?
reduce because it facilitates the reaction between the molecules
39
do enzymes increase or decrease reaction rate?
increase
40
allosteric regulation: inhibition
binding of regulatory subunit to enzyme, changes the shape of the enzymes so substrate can't bind at active site of enzyme
41
competitive inhibition
a molecule similar to the substrate binds to the enzyme and blocks substrate bonding
42
allosteric regulation: activation
binding of regulatory subunit of enzyme, changes the shape of the enzymes and now substrates can bind to the active site of the enzyme
43
what is a type of allosteric activation?
adding a phosphate
44
what can influence enzyme functions?
cofactors such as coenzymes and ATP