Ch 5: Electrons in Atoms/Electrons Flashcards

1
Q

What could Rutherford’s atomic model not explain?

A

The chemical properties of elements.

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2
Q

What did Bohr propose about an electron?

A

It is found only in specific circular paths, or orbits, around the nucleus.

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3
Q

What did Bohr note that atoms emit?

A

Light of specific colors and wavelengths.

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4
Q

What did Bohr determine light came from?

A

Excited electrons when energy is lost.

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5
Q

Electrons could only have certain _________ energies.

A

quantized

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6
Q

What are these characteristics of:

  1. Atoms only emit a few energies of light.
  2. Energy can only have certain specific qualities.
  3. Energy levels are clearly defined values and are not flexible.
  4. If there were any random value, a continuous spectrum of light would be emitted.
A

Quantized energy

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7
Q

What was Bohr correct about? What was Bohr incorrect about?

A

Correct: energy levels.
Incorrect: the orbits.

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8
Q

The energy levels in an atom are not _______ ______. The higher energy levels are ______ ________.

A

equally spaced.

closer together.

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9
Q

Who developed the Quantum Mechanical Model?

A

Erwin Schrödinger.

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10
Q

What does the quantum mechanical model determine?

A

The allowed energies an electron can have and how likely it is to find the electron in various locations around the nucleus.

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11
Q

Electrons in atoms behave like _____.

A

waves.

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12
Q

Electrons: there is a fundamental ___________ about their behavior; cannot map path.

A

uncertainty

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13
Q

Electrons: waves are ___________, but we can assign a location based on ___________.

A

delocalized

probability.

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14
Q

Atomic orbitals: each energy sub level corresponds to an orbital of a different _____, which describes where the electron is likely to be _____.

A

shape

found.

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15
Q

Atomic orbitals: the region where there is a ___ ______ of finding an electron is called an _______.

A

90% chance

orbital.

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16
Q

Atomic orbitals: what are orbitals characterized by?

A

Energy levels and sub levels.

17
Q

What three rules tell how to find the electron configuration of atoms?

A
  1. Aufbau principle
  2. Pauli exclusion principle
  3. Hund’s rule
18
Q

Some actual electron configurations differ from those assigned using the aufbau principle because ____-______ sub levels are not as stable as ______ sub levels. They are more stable than other ______________.

A

half-filled
filled
configurations.

19
Q

What are the 5 properties of waves?

A
  1. speed
  2. wavelength
  3. frequency
  4. energy
  5. hertz
20
Q

The __________ and _________ of light are inversely proportional to each other.

A

wavelength

frequency

21
Q

What type of waves does the electromagnetic spectrum include?

A

Radio waves, microwaves, infrared waves, visible light, ultraviolet waves, X-rays, and gamma rays.

22
Q

What is the electromagnetic spectrum?

A

The full range of electromagnetic energy (waves of electric and magnetic fields, oscillating at right angles to each other).

23
Q

What is the dual nature of light?

A

Light is made up of matter and waves.

24
Q

When atoms absorb energy, electrons move into ____ energy levels.
These electrons lose the energy by emitting _____ when they return to lower energy levels.

A

high

light

25
Q

According to the Aufbau principle, in the ______ _____, electrons have the lowest energy level possible.

A

ground state

26
Q

Each energy level () has a certain number of sub levels (, _, _, _).

A

n

s, p, d, f

27
Q

Each sub level has a certain number of orbitals (_, _, _, _).

A

1, 3, 5, 7

28
Q

Two electrons can share an orbital only if they have ________ _____.

A

opposite spins

29
Q

At the highest energy level, the electrons will ______ ___ to be ________ where possible. All ________ electrons will have the ____ spin.

A

spread out
unpaired
unpaired
same

30
Q

A _______ of energy in the form of _____ is emitted when the electron drops back to a lower energy level. This single step is known as __________ __________.

A

quantum
light
electronic transition

31
Q

The light emitted by an electron moving from a higher to a lower energy level has a _________ directly proportional to the ______ ______ of the electron.

A

frequency

energy change

32
Q

Classical mechanics adequately describes the motions of bodies much ______ than atoms, while quantum mechanics describes motions of _________ _________ and _____ as waves.

A

larger
subatomic particles
atoms

33
Q

Quantum mechanics is considered the _____ theory.

Classical mechanics is considered the _____ theory.

A

newer

older

34
Q

Planck discovered _____ _______ (E=hf).

A

light photons

35
Q

Einstein said: light has ____; it is ______ (E=mc^2).

A

mass

matter

36
Q

DeBroglie said: As the mass _________, the __________ decreases. Electrons behave like _____.

A

increases
wavelength
waves.