cellular respiration Flashcards
Compounds
Atoms exchange electronswith other elements to form compounds
The type of compound formed depends on the electronegativity (EN) of elements involved
Ionic compounds
large EN difference
Covalent (molecular) compounds
small electronegativity difference
Polar covalent bonds
- Small difference in electronegativity between atoms
- Unequal sharing of electrons
Non-polar covalent bonds
- Two atoms of the same electronegativity
- Equal sharing of electrons
Oxidation-reduction reactions
Involve electron transfers
The breakdown of glucose to CO2 is an oxidation process
- Oxygen (O2) gains hydrogen, thus gains electrons, Electrons reduced in CO2
- Molecules that are oxidised lose electrons
* Carbon is more electron poor when in the form of CO2 compared to glucose
* Carbon is oxidised - Molecules that are reduced gain electrons
* Oxygen is reduced
OIL RIG
Oxidation is loss of H
Reduction is gain of H
Anabolism
is to build
* take molecules and form larger molecules
* Glycogen from glucose
* Peptides from amino acids
Catabolism
is to destroy
* taking molecules and breaking them into smaller ones
* Oxidation of glucose to CO2
* Breakdown of proteins to peptides
ATP
most common carrier molecule
Energy stored in phosphate group bonds - break off group from ATP > release energy > left wit ADP and 3rd phosphate group
Oxidative phosphorylation
the main mechanism of ATP synthesis in human cells
* Electron transport chain
* Chemiosmosis
Chemiosmosis
Before ATP is synthesis, H+ are concentrated in the IMM creating an electrochemical gradient
* Energy is harvest from the flow of H+ down their electrochemical gradient
* Energy is used by ATP synthase to combine ADP + Pi -> ATP
Electron transport chain
- Electrons donated by NADH & FADH2 move through protein complexes
- Protein complexes is reduced then oxidised, releasing energy which is used to pump concentrates H + in the intermembrane space
- Electrons eventually fall to O2 and combine with protons to form water
- PROTONS pumped from matrix to IMM
Nicotinamide adenine dinucleotide
- NADH (reduced form): carries electrons and is a good electron donor
- NAD + (oxidised from): not carrying electrons and is a good electron acceptor
Flavin adenine dinucleotide
- FADH2 (reduced form): carries electrons and is a good electron donor
- FAD (oxidised form): not carrying electrons and is a good electron acceptor