Catalysis + use of energy Flashcards

1
Q

what is a carrier molecule

A

molecule with energy rich covalent bonds where energy stored

diffuse rapid throughout cell for biosynthesis + activities

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2
Q

how do coenzyme or activated carrier molecule store energy

A

easily exchangeable form

as chemical groups or high energy electrons

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3
Q

what does ATP mean

A

adenosine triphosphate

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4
Q

how are the phosphate bonds linked in ATP

A

by phosphoanhydride bonds

which release large energy amount when broken down

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5
Q

why is the terminal phosphate group frequently split off by hyrolysis

A

transport itself to other molecules

releases energy for biosynthetic routes

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6
Q

how much energy released by ATP hydrolysis

A

-7.3kcal –> drive energetically unfavourable reaction

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7
Q

what other can ADP can ATP be hydrolysed to

A

AMP + PPi (pyrophosphate)

which is hydrolysed again –> gives more energy

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8
Q

what does NAD stand for

A

Nicotinamide dinucleotide

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9
Q

what is NAD and where is it used

A

coenzyme/ activated carrier molecule
used in oxidation/reduction reactions
carry high energy electrons + H atoms

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10
Q

what does coA do + acetyl coA do

A

caries acetyl group is ready transfer linkage to form acetyl coA
acetyl coA adds 2 C atoms in biosynthesis of larger molecules

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11
Q

ATP coenzyme carries what group

A

phosphate

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12
Q

NADH + FADH carry what group

A

electrons + hydrogens

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13
Q

Acetyl coA carries what group

A

acetyl

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14
Q

carboxylated biotin carries what group

A

carboxyl

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15
Q

S adenosylmethionine carries what group

A

methyl

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16
Q

uridine diphosphate glucose carries what group

A

glucose

17
Q

what does catabolism mean + why is it need

A

breakdown of complex molecules by living organisms with release of energy
generate useful forms of energy for the cell + make small molecules the cell needs

18
Q

what is anabolism mean

A

constructive biochemical processes in living organisms

involves formation of complex molecules from simpler ones for energy storage

19
Q

what is the energy released from catabolism used for

A

synthesis of molecules

20
Q

what is free energy

A

measure of energy contained in a molecule

due to vibration, rotation + energy stored in bonds that can be broken

21
Q

what does delta G mean

A

change in free energy occurring in reaction

22
Q

what does exergonic mean

A

metabolic/chemical process accompanied by release of energy

23
Q

what does endergonic mean

A

metabolism/chemical process accompanied or needing energy absorption

24
Q

what is the change in free energy for a exergonic reaction + why is it important

A

negative delta G

negative delta G needed for a reaction to be spontaneous (energetically favourable reaction is spontaneous)

25
Q

what is the change in free energy for a endergonic reaction

A

positive delta G

26
Q

what is a catalyst and what is its role

A

substance that can lower the a nivation energy of a reaction

increases Ror –> larger proportion of molecules to have energy greater the Ea needed for successful collision

27
Q

what is a coupled reaction

A

energetically favourable reaction used to drive energicatlly unfavourable reaction
involves production of activated carrier molecule or energy storage molecule

28
Q

give a example of a energetically favourable + unfavourable reaction

A

oxidation of glucose = favourable

joining 2 AA together = unfavourable