Carbohydrates Flashcards

0
Q

orientation of the –H and –OH groups around the carbon atom adjacent to the terminal primary alcohol carbon determines whether the sugar belongs to the D (-OH on the left hand side) or L (-OH on the right hand side) series. True or false?

A

False. D pag right, L pag left

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1
Q

Carbohydrates are aldehyde or ketone derivatives of monohydric alcohol. True or false?

A

False. Polyhydric dapat

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2
Q

most sugars occurring in mammals are L sugars

A

False. D sugars dapat. L sugars:amino acid

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3
Q

the ring structures of monosaccharides are similar to the ring structures of either pyran (a 5-membered ring) or furan (a 6-membered ring), true or false?

A

False. Pyran:6-membered ring + Furan:5-membered ring

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4
Q

spontaneous interconversion of α and β anomers of a sugar

A

Mutarotation

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5
Q

α-D-Glucopyranose has –OH group below the plane & β-D-Glucopyranose has –OH group above the plane. T or F?

A

T

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6
Q

True of anomeric carbon atom

A.Cyclic structure exhibits isomerisms here
B.anomeric carbon atom is usually between two H atoms
C.also called carbonyl atom

A

B.anomeric carbon atom is usually between two H atoms

Usually between two O atoms siya

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7
Q

the ring structure of an aldose is a hemiacetal, since it is formed by combination of an aldehyde and ___group. Similarly, the ring structure of a ketose is a hemiketal

A

An alcohol

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8
Q

What are epimers?

A

isomers that differ in configuration at only 1 chiral center

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9
Q
Which is false?
A. Glucose and mannose are epimers
B. Glucose and galactose are epimers
C. Galactose and mannose are epimers
D. All are true.
A

C. Galactose and mannose are epimers

galactose and mannose are NOT epimers – they differ in the position of –OH groups at two carbons

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10
Q

Glucose and fructose exhibit aldose-ketose isomerism. Which is the aldose sugar and which is the ketose one?

A

Glucose-aldose

Fructose-ketose

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11
Q

a hydrogenated form of carbohydrate whose carbonyl group is attached to a primary or secondary hydroxyl group. What is this??

A

Sugar alcohol

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12
Q

Most popular sugar alcohol

A

xylitol

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13
Q

Derivatives of monosaccharides may be utilized in glycolysis, pentose phosphate pathway and uronic acid pathway. True or false?

A

True

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14
Q
Which is not found in the human body?
A.ribose
B.ribulose
C.lyxose
D.arabinose
A

Arabinose! It is found in wood gum.
Lyxose is found in heart muscle
Ribulose is formed in the pentose phosphate pathway

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15
Q

compounds formed by condensation between the hydroxyl group of the anomeric carbon of a monosaccharide, and a second compound that may or may not be another monosaccharide.

A

Glycosides

16
Q

the extent to which starch in foods is hydrolyzed by amylase

A

Glycemic index

17
Q

Lower glycemic index means ___ breakdown of the carbohydrate

Slower,faster

18
Q

Why does our body store glycogen instead of glucose?

A

Glucose will be immediately consumed by the body unlike glycogen which can travel further without being utilized.

19
Q

Two types of glycosidic bonds

A

O-glycosidic

N-glycosidic

20
Q
  • if sugar attaches to a ___ group in the non-carbohydrate molecule, the structure is an N-glycoside and the bond is an N-glycosidic bond
21
Q

[AMINO SUGARS]
Glucosamine – constituent of _____
Galactosamine – constituent of ___

A

first blank:hyaluronic acid

Second blank:chondroitin

22
Q

streptomycin contains __-glycosidic bond

23
Q

Maltose is made of what monosaccharides?how are they linked?

A

Glucose and glucose, C1 of one glucose is linked to C4 of the other

24
False about lactose A)glucose + galactose B)with galactose having β-glycosidic bond with c-4 of glucose (called a β (1-->4) link) C)not capable of mutarotation
C)not capable of mutarotation Since it has free anomeric carbon, it is capable of mutarotation
25
False about sucrose A.two anomeric OH group of glucose and fructose have a glycosidic bonds - B.reducing sugar C.glucose + fructose
B.reducing sugar
26
What is the major sugar of insect hemolymph?
Trehalose
27
``` Which is not a homopolysaccharide? A.starch B.chitin C.cellulose D.proteoglycan ```
D.proteoglycan | Proteoglycan: heteropolysaccharide
28
Two chief components of starch
Amylose | Amylopectin
29
Anong mas marami sa starch, amylose or amylopectin?
Amylopectin
30
Glycogen is ___ (more,less) branched than amylopectin
More
31
Most stable conformation of both starch and glycogen is __
Helix
32
False about chitin A)found in mollusks, crustaceans B)important structural polysaccharide of invertebrates C)consists of N-acetyl-D-galactosamine units
C)consists of N-acetyl-D-galactosamine units | Glucosamine dapat
33
False about cellulose A)homopolymer B)chief constituent of the framework of bacteria C)insoluble and consists of β(1,4) bonds forming long straight chains strengthened by cross-linked hydrogen bonds
B)chief constituent of the framework of bacteria Plants dapat imbes na bacteria
34
False about glycosaminoglycans A)contain a repeating disacchaide unit: GalNAc or GlcNAc + glucoronate or iduronate B)highly positively charged molecules, imparts high viscosity to the solution C)located primarily on the surface of cells or the extracellular matrix (ECM)
B)highly positively charged molecules, imparts high viscosity to the solution Dapat imbes na positive,negative
35
Proteoglycans are also called__
Mucopolysaccharides