Carbohydrates Flashcards
orientation of the –H and –OH groups around the carbon atom adjacent to the terminal primary alcohol carbon determines whether the sugar belongs to the D (-OH on the left hand side) or L (-OH on the right hand side) series. True or false?
False. D pag right, L pag left
Carbohydrates are aldehyde or ketone derivatives of monohydric alcohol. True or false?
False. Polyhydric dapat
most sugars occurring in mammals are L sugars
False. D sugars dapat. L sugars:amino acid
the ring structures of monosaccharides are similar to the ring structures of either pyran (a 5-membered ring) or furan (a 6-membered ring), true or false?
False. Pyran:6-membered ring + Furan:5-membered ring
spontaneous interconversion of α and β anomers of a sugar
Mutarotation
α-D-Glucopyranose has –OH group below the plane & β-D-Glucopyranose has –OH group above the plane. T or F?
T
True of anomeric carbon atom
A.Cyclic structure exhibits isomerisms here
B.anomeric carbon atom is usually between two H atoms
C.also called carbonyl atom
B.anomeric carbon atom is usually between two H atoms
Usually between two O atoms siya
the ring structure of an aldose is a hemiacetal, since it is formed by combination of an aldehyde and ___group. Similarly, the ring structure of a ketose is a hemiketal
An alcohol
What are epimers?
isomers that differ in configuration at only 1 chiral center
Which is false? A. Glucose and mannose are epimers B. Glucose and galactose are epimers C. Galactose and mannose are epimers D. All are true.
C. Galactose and mannose are epimers
galactose and mannose are NOT epimers – they differ in the position of –OH groups at two carbons
Glucose and fructose exhibit aldose-ketose isomerism. Which is the aldose sugar and which is the ketose one?
Glucose-aldose
Fructose-ketose
a hydrogenated form of carbohydrate whose carbonyl group is attached to a primary or secondary hydroxyl group. What is this??
Sugar alcohol
Most popular sugar alcohol
xylitol
Derivatives of monosaccharides may be utilized in glycolysis, pentose phosphate pathway and uronic acid pathway. True or false?
True
Which is not found in the human body? A.ribose B.ribulose C.lyxose D.arabinose
Arabinose! It is found in wood gum.
Lyxose is found in heart muscle
Ribulose is formed in the pentose phosphate pathway
compounds formed by condensation between the hydroxyl group of the anomeric carbon of a monosaccharide, and a second compound that may or may not be another monosaccharide.
Glycosides
the extent to which starch in foods is hydrolyzed by amylase
Glycemic index
Lower glycemic index means ___ breakdown of the carbohydrate
Slower,faster
Slower
Why does our body store glycogen instead of glucose?
Glucose will be immediately consumed by the body unlike glycogen which can travel further without being utilized.
Two types of glycosidic bonds
O-glycosidic
N-glycosidic
- if sugar attaches to a ___ group in the non-carbohydrate molecule, the structure is an N-glycoside and the bond is an N-glycosidic bond
-NH
[AMINO SUGARS]
Glucosamine – constituent of _____
Galactosamine – constituent of ___
first blank:hyaluronic acid
Second blank:chondroitin
streptomycin contains __-glycosidic bond
O
Maltose is made of what monosaccharides?how are they linked?
Glucose and glucose, C1 of one glucose is linked to C4 of the other