bonding ✓ Flashcards
how does covalent bonding happen ?
- two non-metals
- they cannot give or take electrons so they SHARE their electrons
- this creates an ion
how does ionic bonding happen ?
- happens between metals and non metals
- metals want to lose electrons and non-metals want to gain them
- this creates two ions
what does the acronym OILRIG mean ?
Oxidation Is Loss (of electrons) Reduction Is Gain (of electrons)
if when formed the ion has lost (2) electrons what is its charge ?
(2) +
if when formed the ion has gained (2) electrons what is its charge ?
(2) -
how to work out a formula for the compounds formed if they balance eg Li+ and F- ?
LiF
how to work out a formula for the compounds formed if they don’t balance eg Li+ and F2- ?
- both both go into 2
- times the Li+ by 2 and times the F2- by 1
- this makes Li2F
how to define and ionic bond ?
- the string electrostatic attraction between oppositely charged ions
why do giant ionic lattices have high melting and boiling points ?
- the electrostatic attraction between the oppositely charged ions its very strong
- takes a large amount of energy to pull them apart
- so they have a high melting and boiling point
why do ionic substances conduct electricity only when they are molten or dissolved (aqueous) ?
- ionic substances do not have electrons that can move but they do have ions
- the problem is that in a lattice these are unable to move
- however if the substance is made molten the ions can move
- also is the substance is aqueous then the ions can move
how to define a covalent bond ?
- electrostatic attraction between a pair of shared electrons and the nuclei of the atoms
why do simple covalent structures have a low melting and boiling and are unable to conduct electricity ?
- they have low melting and boiling points because the force in the molecules are weaker
- they cannot conduct electricity because they have no free moving electron or ion
what is the trend between boiling point and the length of the molecule ?
the longer the molecule the boiling points it has
what is the structure of diamond and graphite ?
giant covalent structures
what are the properties of diamond ?
- made up of carbon
- each carbon atom in a diamond has four bonds
- these are all strong and covalent
- there are lots of bonds so lots of energy is needed to break them
- so it has a high melting and boiling point
- they are strong because any pressure applied spreads out around the structure
- they are brittle (do not like being knocked)
what are the properties of graphite ?
- made up of carbon
- each carbon atom in graphite has 3 bonds
- they form a planar (flat) hexagonal structure
- the layers are able to slide over each other
- makes them useful in industry as a solid lubricant
- has high melting and boiling points it is made up of lots of strong covalent bonds that require large amounts of energy to break them
- has a lower melting and boiling point that diamond
what is a very common question when talking about the melting and boiling points of molecules, eg AlF3 and SrBr2 ?
- AlF3 has 3+ and 3- charges
- SrBr2 has 2+ and 2- charges
- AlF3 therefore has a stronger electrostatic attraction
- this means that more energy is needed to break the AlF3 bonds
- therefore AlF3 has higher melting and boiling points