Atomic and Nuclear Phenomena Flashcards

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1
Q

the ejection of an electron from the surface of a metal in response to light

A

photoelectric effect

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2
Q

the minimum light frequency necessary to eject an electron from a given material

A

threshold frequency (ƒ(T))

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3
Q

light quanta that are present in an integral number in a light beam; have energy proportional to frequency of light

A

photons

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4
Q

relationship of energy to frequency of light:

A

E = hƒ

where:
E = energy of photon of light
h = Planck’s constant (6.626x10^-34 J*s)
ƒ = frequency of light

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5
Q

maximum kinetic energy of ejected electron:

A

K(max) = hƒ - W

where:
h = Planck’s constant (6.626x10^-34 J*s)
ƒ = frequency of light
W = work function of metal in question

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6
Q

the minimum energy necessary to eject an electron from a given metal; its value depends on the metal used and can be calculated by multiplying the threshold frequency by Planck’s constant

A

work function

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7
Q

work function:

A

W = h ƒ(T)

where:
h = Planck’s constant (6.626x10^-34 J*s)
ƒ(T) = threshold frequency

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8
Q

states that electron energy levels are stable and discrete, corresponding to specific orbits

A

Bohr model of the atom

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9
Q

an electron can jump form a lower-energy to a higher-energy orbit by ____ a photon of light of the same frequency as the energy difference between the orbits

A

atomic absorption (absorbing)

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10
Q

when an electron falls from a higher-energy to a lower-energy orbit, it ____ a photon of light of the same frequency as the energy difference between the orbits

A

atomic emission (emits)

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11
Q

may be impacted by small changes in molecular structure

A

absorption spectra

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12
Q

occurs when a species absorbs high-frequency light and then returns to its ground state in multiple steps; each step has less energy than the absorbed light and is within the visible range of the electromagnetic spectrum

A

fluorescence

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13
Q

the amount of energy that is released when nucleons (protons and neutrons) bind together

A

nuclear binding energy

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14
Q

the strong and weak nuclear forces (which contribute to the stability of the nucleus), electrostatic forces, and gravitational forces

A

four fundamental forces of nature

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15
Q

the difference between the mass of the unbonded nucleons and the mass of the bonded nucleons within the nucleus; the unbonded constituents have more energy and, therefore, more mass than the bonded constituents; is the amount of mass converted to energy during nuclear fission

A

mass defect

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16
Q

equivalence of matter and energy:

A

E = mc^2

where:
E = energy
m = mass
c = speed of light (3x10^8 m/s)

17
Q

isotopic notation

A

elements are preceded by their atomic number (Z) as a subscript and mass number (A) as a superscript

where:
X = element
A = mass number (corresponds to number of protons plus number of neutrons)
Z = atomic number (corresponds to number of protons)

18
Q

occurs when small nuclei combine into larger nuclei; energy is released because nuclei formed is more stable than starting nuclei

A

fusion

19
Q

occurs when a large nucleus splits into smaller nuclei; energy is released because nuclei formed is more stable than starting nuclei

A

fission

20
Q

the loss of small particles from the nucleus; naturally occurring spontaneous decay of certain nuclei accompanied by the emission of specific particles

A

radioactive decay

21
Q

radioactive decay:
represent nuclear isotopes; parent nucleus __ undergoes nuclear decay to form a daughter nucleus __; sum of atomic numbers and mass numbers must be same on both sides of equation

A

X and Y

22
Q

radioactive decay:

generic balanced equation:

A
23
Q

radioactive decay:

the emission of an ____ particle, which is a He nucleus that consists of two protons, two neutrons, and zero electrons

A

alpha (α) decay

24
Q

radioactive decay:

alpha (α) decay balanced equation:

A
25
Q

radioactive decay:

the decay of a neutron into a proton, with emission of an electron (e-, __) (Z = -1, A = 0)

A

beta-negative (β-) decay

26
Q

radioactive decay:

beta-negative (β-) decay balanced equation:

A
27
Q

radioactive decay:

the decay of a proton into a neutron, with emission of a positron (e+, __) (Z = +1, A = 0)

A

beta-positive (β+) decay

28
Q

has the mass of an electron but carries a positive charge

A

positron (e+, β+)

29
Q

radioactive decay:

beta-positive (β+) decay balanced equation:

A
30
Q

radioactive decay:
the emission of a ____ ray (a high-energy (high-frequency) photon), which converts a high-energy nucleus into a more stable nucleus; carry no charge and simply lower the energy of the parent nucleus without changing the mass number or atomic number

A

gamma (𝛾) decay

31
Q

radioactive decay:

gamma (𝛾) decay balanced equation:

A
32
Q

radioactive decay:
the absorption of an electron from the inner shell that combines with a proton in the nucleus to form a neutron; can be thought of as reverse of beta-negative (β-) decay

A

electron capture

33
Q

radioactive decay:

electron capture balanced equation:

A
34
Q

the amount of time required for half of a sample of radioactive nuclei to decay

A

half-life (T(1/2))

35
Q

how the number of radioactive nuclei changes with time; the rate at which radioactive nuclei decay is proportional to the number of nuclei that remain

A

exponential decay

36
Q

rate at which nuclei decay:

A

∆N/∆t = -λn

where:
∆N/∆t = rate at which nuclei decay
λ = decay constant
n = number of radioactive nuclei that have not yet decayed

37
Q

exponential decay:

A

n = n(o) e^-λt

where:
n = number of radioactive nuclei that have not yet decayed
n(o) = number of undecayed nuclei at time t = 0
λ = decay constant
t = time

38
Q

decay constant relation to half-life:

A

λ = ln 2 / T(1/2) = .693 / T(1/2)

where:
λ = decay constant
T(1/2) = half-life