Alkenes Flashcards

1
Q

What are alkenes

A

Unsaturated hydrocarbons that contain at least one carbon double bond

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2
Q

What is the general formula for alkenes

What type of alkene is the exception

A

CnH2n

Cyclic alkenes

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3
Q

What is an electrophile

A

And electron deficient species (will accept a lone pair of electrons)

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4
Q

When do alkenes undergo addition reactions

What is the mechanism called

A

When they are attacked by electrophiles

Electrophilic addition

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5
Q

What is a carbocation

A

An ion with a positively charged carbon atom

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6
Q

How do you test for alkenes

A

Add a few drops of bromine water to the test liquid and shake it

If a carbon carbon double bond is present then it will turn from orange to colourless

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7
Q

What is an intermediate

A

Something that is formed in one step and then used up in another

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8
Q

What is the relation between a carbocation and the number of alkyl groups it is bonded to

A

The more alkyl groups it’s bonded to the more stable the carbocation is because alkyl groups are electron realising so stabilise the positive charge

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9
Q

How is a polymer formed

A

When thousands of repeating units made from small molecules called monomers join together to form a long chain molecule

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10
Q

What happens during addition polymerisation

A

Unsaturated molecules ie alkenes add together to form polymers

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11
Q

How are polymers named

A

Add the word poly as a prefix in front of monomer name for example Ethernet becomes polyethene

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12
Q

What is the repeating unit

A

The part of the polymer whose repetition would produce the complete polymer chains

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13
Q

What should you remember when drawing repeating units

A

Don’t include the n
Extend lines out of brackets

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14
Q

What is the reactivity of addition polymers

A

They tend to be unreactive because they are saturated and usually non polar as there is no C with a delta plus charge

For them to react the carbon carbon bonds would have to be broken which are extremely strong

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15
Q

What are the intermolecular forces between polymer chains

A

Usually weak intermolecular forces ie van der waals or permanent dipole dipole forces

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16
Q

What happens if you increase the branching in addition plumuners

A

Reduces strength of intermolecular forces because the polymer chains have fewer points of contact as they can’t pack as close together so the van der waals forces are weaker

17
Q

What intermolecular forces are in polychloroethene (pvc)

A

Van der waals and pdd because there is a polar C-Cl bond

18
Q

What are 3 uses of the hard and rigid form of pvc

A

Drain pipes
Ceiling tiles
Window frames

19
Q

How can pvc be made not rigid

What is it used for

A

Adding a plasticiser to make uPVC which will allow the chains to slide and therefore making the polymer flexible

They are used in window frames