Acids, bases, salts and ionization Flashcards
- A water molecule is able to self-ionize.
- In pure water, a very small amount of water molecules ionize into hydrogen (proton) and hydroxide.
- There are always equal parts of H+ and OH- in pure water.
- Therefore the pH of water is neutral (7).
Hydrogen and Hydroxide ions
The measurement of H+ in a solution.
- Equal amounts of H+ and OH- is a neutral solution and has a pH of 7.
- pH of less than 7 are acidic, more H+ than OH-
- Less H+ than OH- is a basic solution, pH is greater than 7
pH
The amount of H+ in a solution is calculated as a molar concentration.
- 1 mole = 6.023 X 10 to the 23rd.
Determining the pH
Compounds that release H+ in a solution.
- Adding this to water will lower the pH.
- Dissociates in water :
HA => A- + H+
Acids
Compounds that release OH- in a solution.
- Adding this to water will increase the pH.
- Dissociate in water
- React with water to produce OH-
- General formula:
XOH => X+ + OH-
Bases
- Appear as all three states of matter, but liquid is most common.
- Pure molecules are usually dry crystals and are extremely hygroscopic.
- Binary
- Ternary
General properties of acids
Pull water out of the air to them.
Hygroscopic
Contain H+ and one other non-metal (HCl, HF, HBr)
Binary acids
Contain H+, O, and one non-metal radical.
Ternary acids
- Also called alkaline compound
- Bitter taste (physical property)
- Bases can appear in all three states, but most commonly found as greasy, slippery, powder form.
- All ternary compounds because they all contain O and a metal.
General properties of bases
States that acids dissociate into an aqueous solution to yield H+ and bases dissociate into an aqueous solution to yeild OH-
- The most commonly used biochemical definition for an acid and base.
Arrhenius theory
Defines acids as proton donors and bases as proton acceptors.
- Conjugate acid-base pairs differ by a single proton
- Amphorteric compounds can act as either a base or an acid.
Bronstead- Lowery Theory
States that an acid is any substance that accepts a pair of electrons and a base is any substance that donates a pair of electrons.
Lewis theory
- Acids can be added to basic solutions to decrease the pH
- Bases an be added to acidic solutions to increase the pH
- A neutralization reaction results in a pH of 7.
Acid-base reactions
A reaction with the product being a salt and water.
Neutralization