Acids And Bases Part 1 Flashcards

1
Q

What does bronsted Lowry theory describe acids and bases in terms of

A

Protons

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2
Q

What does an acid-base reaction involve

A

Proton transfer

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3
Q

Acid

A

A substance that donates H+ ions

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4
Q

What are acids classified as strong or weak depending on

A

The extent of dissociation

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5
Q

Strong acid

A

Completely dissociates in solution

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6
Q

Weak acid

A

Partially dissociates in solution

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7
Q

Base

A

A substance that accepts H+ ions

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8
Q

Alkali

A

A base that releases hydroxide ions in aqueous solution

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9
Q

What type of reaction is that of acids with metals

A

Redox

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10
Q

What is the role of H+ ions in the reaction of acids with metals

A

Oxidising agent

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11
Q

What are acid base equilibria

A

Reversible reactions involving the transfer of protons

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12
Q

pH

A

-log[H+]

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13
Q

What does a low pH mean

A

Larger concentration of H+ ions

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14
Q

What does a high pH mean

A

A small concentration of H+ ions

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15
Q

[H+]

A

10 ttp -pH

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16
Q

How many moles of H+ ions does one mole of a monoprotic acid donate

17
Q

What do you assume in pH calculations for strong acids

A

Complete ionisation

18
Q

What does it mean that for pH calculations of strong acids, you assume complete ionisation

A

[H+]=original conc of acid

19
Q

Is sulfuric monoprotic

A

Diprotic

[H+]=2[HA]

20
Q

What are a weak acids undissociated molecules in equilibrium with

A

It’s ions

21
Q

Acid dissociation constant

22
Q

Ka

A

Conc product/conc reactants

23
Q

Units of Ka

24
Q

What is the value of Ka a quantitative measure of

A

The strength of a weak acid

25
What is the relationship between degree of dissociation and Ka value and why
Greater degree of dissociation, higher conc of H+ and larger Ka value
26
What is pKa sometimes used for
To compare the relative strengths of acids
27
pKa
-logKa
28
Relationship between Ka value and strength of acid
Higher Ka value = stronger acid
29
Relationship between pKa value and acid strength
Lower pKa value = stronger acid
30
Expression for ionisation of water
h20 > H+ + OH-
31
To what extent does pure water ionise to
A very small extent
32
What is Kw derived from
The equilibrium constant for the dissociation of water into H+ ions and OH-
33
Definition of Kw
[H+][OH]
34
What is Kw at 298K
1x10-14 mol2dm-6
35
Why is the dissociation of water an endothermic process
Energy is required to break bonds
36
Why does Kw increase when temperature increases
The equilibrium moves to the right
37
Assumptions to make to calculate the pH of a strong base
- assume complete ionisation | - assume Kw= 1x10-14