Acids and Bases Flashcards
Arrhenius Theory
Acid - substance that forms the hydronium ion in water.
Base - substance that forms the hydroxide ion in water.
Pros - Easy to sort a + b
Cons - Many bases don’t contain hydroxides
Bronsted Lowry Theory
Acid - donates a proton, becomes conjugate base
Base - accepts a proton, becomes a conjugate acid
Lewis Theory
Acid - accepts an electron pair around central atom
Base - donates an electron pair from around central atom
Polyprotic
2+ protons
coordinate covalent bond
both electrons donated by a single substance
How much is ionized in a strong rxn?
100%
How much is ionized in a weak rxn?
> 100%
Binary Acids vs Tertiary Acids
Binary - 2 elements
Tertiary - 3 elements
Per _ ate —>
Per _ ic acid
_ate —>
_ic
_ite —>
___ous
Hypo_ite —>
Hypo _ ous
_ide
Hydro_ic
Strong Acids
HCl, HBr, HI, HNO3, H2SO4, HClO3, HClO4
Strong Bases
OH- with a metal from Group 1 or 2, except Be & Mg
Strong acids and bases are ___ conductors
good
How many arrows to use for strong and weak?
strong = 1
weak = 2
H+ > OH-
acidic
H+ < OH-
basic
H+ = OH-
neutral
pH —> pOH
pH + pOH = 14
pOH to OH-
10 ^-pOH
OH - to pOH
-log (OH-)
H+ to OH - and vice versa
H+ x OH- = 1 x 10^-14
H+ to pH
-log H+
pH to H+
10^-pH
You must show ___ in a weak acid dissosciation equation
Water
You must show ___ in a weak acid dissociation equation
Water
How do conjugate acids/bases differ from their OGs?
By one proton
Amphiprotic
Can donate or accept a proton (act as acid or base)
Most common amphiprotic substance
water
Amphoteric
Can react with both acids and bases
Polyprotic Acids
Can give more than one H+ ion away. H2S, H2CO3
What is titration
A technique used to determine the unknown molarity of an acid or base. Solution of known molarity is dropped to the other solution until a neutralization rxn takes place
Equivalence Point
When all of the acid is neutralized by the base - end of titration
Indicators
show when the equivalence point is used. Most common indicator is phenophaletin.
Buffers
Solutions that resist changes in pH / keep it constant. Usually weak acid + conjugate base / vice versa.