A2: Acids and bases Flashcards
Bronsted-Lowry acid
proton donor
Bronsted-Lowry base
proton acceptor
What is a conjugate acid-base pair
Two species that can be interconverted by the transfer of a proton
Hydronium ion formula
H3O+
The number of hydrogen ions in the acid which can be replaced defines the acid as:
Monobasic, dibasic, tribasic
pH=
-log[H+]
[H+]=
10^-pH
Kw=
[H+][OH-]
Kw (ionic product of water) value
1x10^-14
Ka expression
[H+][A-]/[HA]
pKa=
-log(Ka)
Ka=
10^-pKa
Ka expression after assumptions
[H+]^2/[HA]
Assumptions needed to simplify the Ka expression
[H+]=[A-] (neglecting dissociation from water)
[HA]initial = [HA]equilibrium
Equivalence point
Volume of one solution that exactly reacts with the volume of the other solution
What is an acid-base indicator
A weak acid, HA that has a very different colour to its conjugate base
Strong acid - strong base indicator
phenolphthalein or methyl orange
Wek acid - strong base indicator
phenolphthalein
Strong acid - weak base indicator
methyl orange
Weak acid - weak base indicator
None