A1: Group 2 Flashcards
Group 2 redox reactions with oxygen
Forms metal oxides, MO
Group two outer electrons configuration
Each has two outer shall electrons, in the outer s sub-shell
Group 2 redox with water
Forms an alkaline hydroxide ( general formula = M(OH)2) and H2
Group 2 redox with dilute acids
Forms a salt and hydrogen
Group two trend in reactivity
As you go down the group atomic radium increases and shielding increases, which decreases nuclear attraction, decreasing first and second ionisation energies, and increasing reactivity
Reaction of group 2 oxides and water
CaO(s)+H2O(l)–>Ca2+(aq) + 2OH-(aq)
What happens when a solution of a group two oxide and water becomes too saturated?
Any further metal and hydroxide ions will form a solid precipitare, for example Ca(OH)2(s)
Solubility and pH of group two hydroxides
Solubility increases down the group, so resulting solutions contain more OH-(aq) ions, and a higher pH
What is the approximate pH of Mg(OH)2(s) in solution and why?
Around ten, because it is only slightly soluble in water so has a low OH-(aq) concentration
Group 2 experiment to find the trend in solubility and pH
1) Add a spatula of each group 2 oxide to water in test tubes and shake
2) There will be insufficient volume of water to dissolve all of the metal hydroxide that forms, so some undissolved solid will remain
3) Measure the pH of each
Uses of Ca(OH)2
In agriculture it is added to fields as lime by farmers, which increases the pH of acidic soils
Equation of agricultural use of Ca(OH)2
Ca(OH)2(s)+2H+(aq)–>Ca2+(aq) + 2H20(l)
Uses of group two bases in medicine
Used as antacids for treating acid indigestion, Mg(OH)2, Mg and Ca carbonates neutralise HCl