8.1 Film Processing Part 2 Flashcards
is the first step in wet processing a film
Developing
At this stage silver is
deposited at the latent image sites and an image becomes visible
Developing
The primary agents of the developer are two ______ agents, although
automatic radiographic developer solutions also include an activator,
restrainer, preservative, hardener, and water as a solvent
reducing
Developer time in 90-sec Processor
20-25 sec
The action of the ______ is controlled by the immersion time, solution
temperature, and chemical activity
developer
provide electrons to the silver ions attached to the
sensitivity specks of the silver halide crystals (the latent image)
Reducing agents
Silver halides have negative exteriors (where bromine and iodine ions are located) and positive interiors (where silver ions are located). This
arrangement effectively prohibits the _____ agent from supplying
electrons to the silver ions because the bromine and iodine repel electrons
reducing
reduces latent image to visible black metallic silver
Developer
rapidly produces fine detail shades of gray (Developer)
Phenidone (Reducing Agent)
slowly produces heavy densities
Hydroquinone (Reducing Agent)
produces alkaline pH, swells gelatin (Developer)
Sodium carbonate (Activator)
decreases reducing agent activity, antifogging agent (Developer)
Potassium bromide (Restainer)
controls oxidation, buffer agent (Developer)
Sodium sulfite (Preservative)
hardens emulsion, reduces gelatin swelling (Developer)
Glutaraldehyde (Hardener)
dissolves chemicals for use (Developer)
Water (Solvent)
However, when a sensitivity speck has attracted silver ions, a gate exists through which
the interior of the crystal can be supplied with electrons. When a silver ion obtains an
extra electron, it is converted to a stable black metallic silver atom. _____ is
actually the process of the reducing agents giving up electrons to neutralize the positive
silver ions
Reduction
The secret to the production of the various densities is that the sensitivity speck gate
will be larger when more silver ions are deposited at the speck during exposure. A
larger gate permits ____ reduction of the internal silver atoms. When the reduction
process is stopped at the appropriate time, the silver halides have accumulated black
metallic silver in proportion to the size of the sensitivity speck gate
faster
is used to describe development when these factors
cause unexposed silver halides to be reduced
chemical fog
Those silver halide crystals that have fewer than ____ silver atoms on their
sensitivity specks are unable to open a gate and remain unreduced
(undeveloped).
three
Each reduced silver atom is accompanied by a liberated bromine ion with a
_____ charge. A bromide ion barrier is created when too many liberated
bromine ions are permitted to accumulate. They may produce sufficient
charge to repel reducing agents and effectively stop silver halide
development
negative
known as P developer
phenidone
known as Q
developer
hydroquinone
quickly reduces silver, enhancing fine detail and
subtle shades of gray, and works only in areas of light exposure
phenidone
replaces the function of metol (often known by the Kodak brand
name Elon) in manual processing
phenidone
slowly reduces silver and produces heavy density
Hydroquinone
When the two reducing agents are combined, forming a PQ
developer, their reducing ability is greater than the sum of their
independent abilities. This is a synergistic phenomenon known as
______
superadditivity
are opposite processes
Oxidation and reduction
X loses electrons,
X is oxidized by Y (becomes more positive)
Reducing agent
Y gains electrons,
Y is reduced by X (becomes more negative)
Oxidizing agent
reduces the strength of the developer
solution
oxidation/reduction process
As developer _____, it changes color, first to a deep amber, then
to brown, and, finally, to a thick, rust red
oxidizes
The action of the reducing agents is enhanced by maintaining the developer
solution in an alkaline state (around pH 10.0–10.5) by using an
_____, usually _____
activator,
sodium carbonate
may also be used as an activator
Potassium carbonate, sodium hydroxide, and potassium hydroxide
also assists the reducers in reaching the silver
halides by causing the gelatin to swell and become more permeable
activator
is caustic, and therefore rubber gloves and an apron should be
worn when handling developer solutions
activator
s also added to the developer to
restrict the reducing action to those crystals with sensitivity speck gates
restrainer, usually potassium bromide
is used as a preservative agent to help decrease the
oxidation of the reducing agents when they are combined with air
Sodium sulfite
is the most common developer solution hardener. It controls
the swelling of the gelatin to prevent scratches and abrasions to the
emulsion during processing
Glutaraldehyde
It also maintains uniform film thickness to assist in transport through an
automatic processor
Glutaraldehyde
Excessive _____ may cause the emulsion to harden prematurely,
preventing chemical interactions with the silver halides and trapping
moisture in the gelatin
hardener