7.3 Periodic Trends In Bonding And Structure Flashcards

1
Q

What are the metalloids?

A
Boron 
Silicon 
Germanium 
Arsenic 
Antimony
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2
Q

Which metal is liquid at room temperature?

A

Mercury

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3
Q

One constant property of all metals

A

They can conduct electricity

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4
Q

Describe metallic bonding

A

Each atom donates negative outer shell electrons, which form a sea of delocalised electrons
Positive ions - cations - are left behind
It is the strong electrostatic force of attraction between the cations and delocalised electrons

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5
Q

What maintains the structure of metals?

A

The cations, which are fixed in position

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6
Q

What is a giant metallic lattice?

A

A 3D structure of positive ions and delocalised electrons, bonded together by strong metallic bonds

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7
Q

Properties of metals

A

Strong metallic bonds
High electrical conductivity
High melting and boiling points

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8
Q

Why can metals conduct electricity?

A

The delocalised electrons are free to move

This carries charge across a structure

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9
Q

Why do most metals have high melting and boiling points?

A

The strength of the metallic ones cause the high melting and boiling points
A large amount of energy is required to overcome the strong electrostatic forces of attraction between cations and electrons

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10
Q

Solubility of metals

A

Metals do not dissolve - any interactions with polar water cause reactions, not dissolving

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11
Q

Forces between simple molecular substances?

A

Weak intermolecular forces

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12
Q

MP/BPs of simple molecular structures

A

Low, as the intermolecular forces holding the molecules together are weak, so little energy is required to overcome them

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13
Q

Which non metals form a giant covalent lattice?

A

Carbon
Silicon
Boron

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14
Q

What is a giant covalent lattice?

A

A 3D structure of atoms, bonded together by strong covalent bonds

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15
Q

Structure of Carbon atoms in diamond

A

Tetrahedral arrangement
Bond angle of 109.5
Each Carbon forms bonds with 4 other Carbon atoms

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16
Q

MP/BPs of giant covalent lattices

A

Very high MP/BPs
Covalent bonds are strong
High temperatures are required to overcome these strong bonds

17
Q

Solubility of giant covalent lattices

A

Insoluble in almost all solvents

Covalent bonds holding atoms together are too strong to be broken by interaction with solvents

18
Q

Can giant covalent lattices conduct electricity?

A

No, except graphene and graphite

19
Q

Why can diamond and silicon not conduct electricity?

A

All four outer electrons are covalent bonded

No free electrons are available to move and carry electricity

20
Q

Bond angle in graphene and graphite

A

120

21
Q

What happens to MP from groups 1-3?

A

It increases
Cations have higher charges
More delocalised electrons - lost from the outer shells
Stronger electrostatic force of attraction - higher MP

22
Q

Why is there a sharp decrease in melting point between group 14 and 15?

A

There is a change from giant to simple molecular structures