6.5 Rate Law Flashcards

1
Q

Rate law

A

An equation that connects the rate of the reaction with the concentration of its reactants at a given temperature and pressure.

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2
Q

what does k stand for in the equation

A

k is the rate constant (determined experimentally, and varies with temperature).

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3
Q

what do m and n stand for in the equation

A

Exponents m and n CANNOT be obtained from the balanced equation. CAN only be determined
from experimental data. (m, n >0).

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4
Q

order of reaction

A

Each exponent in the rate law equation (m and n)
is called an ORDER of REACTION. (describes the
relationship between the initial concentration of
the reactant and its rate)

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5
Q

total order

A

TOTAL order is simply the SUM of the individual
orders.

Rate = k[A]1[B]2

1+2 =3

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6
Q

Any number raised to the power of zero is….
ONE. This means that the concentration of
that reactant does ___ affect the _____ of
reaction.

A

not; rate

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7
Q

rate constant

A

determined empirically
and is unique for a single reaction at a
specified temperature

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8
Q

initial rate

A

the rate determined just after
the reaction begins (just after t = 0 s)

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9
Q

If the exponent of [A] is 1, then the reaction is _____ order with respect to A.

A

first

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10
Q

If the exponent of [A] is 2, then the reaction is ________ order with respect to A

A

second

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