6.5 Rate Law Flashcards
Rate law
An equation that connects the rate of the reaction with the concentration of its reactants at a given temperature and pressure.
what does k stand for in the equation
k is the rate constant (determined experimentally, and varies with temperature).
what do m and n stand for in the equation
Exponents m and n CANNOT be obtained from the balanced equation. CAN only be determined
from experimental data. (m, n >0).
order of reaction
Each exponent in the rate law equation (m and n)
is called an ORDER of REACTION. (describes the
relationship between the initial concentration of
the reactant and its rate)
total order
TOTAL order is simply the SUM of the individual
orders.
Rate = k[A]1[B]2
1+2 =3
Any number raised to the power of zero is….
ONE. This means that the concentration of
that reactant does ___ affect the _____ of
reaction.
not; rate
rate constant
determined empirically
and is unique for a single reaction at a
specified temperature
initial rate
the rate determined just after
the reaction begins (just after t = 0 s)
If the exponent of [A] is 1, then the reaction is _____ order with respect to A.
first
If the exponent of [A] is 2, then the reaction is ________ order with respect to A
second