6 equilibria Flashcards

1
Q

what is a reversible reaction?

A

a reaction that can go forwards and backwards

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2
Q

when is equilibrium reached?

A

when there is a balance between the amount of products and reactants
when the concentration of each substance stays constant

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3
Q

why does equilibrium only occur in closed systems?

A

products can’t escape

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4
Q

what is le chateliers principle?

A

if a reaction at equilibrium changes in pressure, temperature or concentration, the position of equilibrium will move to minimise/counteract the change

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5
Q

if equilibrium shifts to the left do you make more products or reactants?

A

reactants

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6
Q

if equilibrium shifts to the right do you make more products or reactants?

A

products

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7
Q

which way would the equilibrium shift if the concentration of a reactant was increased?

A

right

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8
Q

which way will equilibrium shift if the concentration of a product is increased?

A

left

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9
Q

which way will equilibrium shift if pressure is increased?

A

to the side with the fewest moles/gas molecules

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10
Q

which way will equilibrium shift if pressure is decreased?

A

to the side with the most moles/gas molecules

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11
Q

which way will equilibrium shift if temperature is increased?

A

in the endothermic direction

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12
Q

which way will equilibrium shift if temperature is decreased?

A

in the exothermic direction

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13
Q

which way will equilibrium shift if a catalyst is added?

A

catalysts have no effect on equilibrium- it will speed up the rate of both reactions equally

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14
Q

what is the reversible reaction for ethanol?

A

ethene + water -> ethanol
H2C=CH2 + H2O -> CH3CH2OH

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15
Q

what are the conditions for making ethanol?

A

low temp (570K)
high pressure (65000kPa)
phosphoric acid catalyst (H3PO4)

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16
Q

what is a problem of ethanol production?

A

high pressure is expensive

17
Q

what would be the calculation for Kc for
2A + B <-> 2C + D?

A

Kc = [C]2 x [D] / [A]2 x [B]

18
Q

what do the square brackets mean in Kc calculations?

A

concentration of

19
Q

how do you find moles?

A

mass/Mr / conc x vol

20
Q

what does ICE box stand for?

A

initial moles
change in moles
equilibrium moles

21
Q

how does change in temperature affect Kc?

A

if equilibrium shifts to right Kc will increase
if to left, Kc will decrease

22
Q

how does change in concentration affect Kc?

A

no effect

22
Q

what is a homogenous reaction?

A

a reaction where all reactants and products are in the same phase