26 compounds containing carbonyl group Flashcards

1
Q

what is a carbonyl group?

A

C=O

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2
Q

what is the suffix for aldehydes?

A

-al

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3
Q

what is the suffix for ketones?

A

-one

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4
Q

why do carbonyl compounds have higher boiling points than molecules like alkanes?

A

C=O is polar meaning it has permanent dipole dipole forces which are stronger than Van de Waals forces

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5
Q

are ketones and aldehydes soluble? why?

A

shorter chains are as H bonds form between the water and the oxygen on the carbonyl compound

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6
Q

are carbonyl compounds reactive? why?

A

yes because it is polar so nucleophilic reagents can attack the C

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7
Q

what does CN act in a reaction with a ketone and an aldehyde?

A

nucleophile

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8
Q

what does the CN attack in a reaction with a ketone and an aldehyde?

A

the partially positive carbon that is double bonded to the oxygen

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9
Q

what is a carboxyl group?

A

COOH

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10
Q

what is a hydroxyl group?

A

O-H

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11
Q

how do you name carboxylic acids?

A

longest chain-oic acid

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12
Q

is the carboxyl group always carbon 1 or always the last carbon?

A

carbon 1

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13
Q

what type of acid is a carboxylic acid?

A

weak

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14
Q

what do carboxylic acids do due to the fact that they are weak acids?

A

partially dissociate and form an equilibrium reaction

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15
Q

where does equilibrium lie in reactions starting with carboxylic acids?

A

to the left

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16
Q

what is the difference in solubility between long chained and short chained carboxylic acids?

A

long chained- more soluble
short chained- less soluble

17
Q

what can help distinguish between different carboxylic acids?

A

they have different melting points

18
Q

how are esters formed?

A

reaction between:
alcohol and carboxylic acid
OR
acid anhydride and alcohol
(esterification)

19
Q

what is the general formula for esters?

A

RCOOR

20
Q

how do you name esters?

A

(a)-yl (b)-oate
a- group on side of O group
b- group on side of carboxyl group

21
Q

what are the conditions for esterification? (acidic)

A

concentrated H2SO4

22
Q

which esterification reaction is an equilibrium reaction and which is not?

A

COOH + OH = equilibrium
acid anyhdride + OH = forward reaction

23
Q

how do you form carboxylic acids from esters?

A

hydrolysis

24
Q

what 2 types of hydrolysis are there?

A

acid catalysed
base catalysed

25
Q

how does acid catalysed hydrolysis work?

A

ester + water <-> COOH + OH
catalysed by conc H2SO4

26
Q

how does base catalysed hydrolysis work?

A

ester + water <-> COOH + OH + salt
catalysed by warm aqueous NaOH

27
Q

how does a salt form in a base catalysed hydrolysis of an ester?

A

NaOH reacts with carboxylic acid

28
Q

what happens as a result of the salt being mad in a base catalysed hydrolysis of an ester?

A

yield increases so equilibrium shifts to the right

29
Q

how are fats and oils made?

A

glycerol + fatty acid

30
Q

fatty acids can be saturated or unsaturated, what does this mean?

A

saturated have no C=C
unsaturated have one or more C=C

31
Q

what is the IUPAC name for glycerol?

A

propane-1,2,3-triol