5B. Formulae, Equations and Moles [SET 2] Flashcards
What does the Avogadro constant represent?
The number of atoms per mole of the carbon-12 isotope
The number of atoms or molecules that are in a mole of a substance
What is an empirical formula?
Simplest whole number ratio of atoms of
each element present in a compound
How to calculate empirical formula?
● Divide the amount of each element by its molar mass
● Divide the answers by the smallest value obtained
● If there is a decimal, divide by a suitable number to make it into a whole number
State Avogadro’s law
Under the same temperature and pressure, one mole of any gas would occupy the same volume.
What are the ideal ways in which gases behave?
● They are in continuous motion
● No intermolecular forces experienced
● Exert pressure when they collide with each other or container
● No kinetic energy is lost in the collisions
● When temperature increases, kinetic energy of gases also increase
Write down the ideal gas equation (in words and symbols, including the units?
pV = nRT
Pressure (Pa) x volume (m 3 ) = number of moles (mol) x gas constant (8.314 J mol -1 ) x temperature (K)
1 atmospheric pressure is equal to how many pascal?
1 atm = 101325 Pa
0°C is equal to how many kelvin?
273 K
What is a standard solution?
A solution of known concentration
Write down the steps to prepare a standard solution
- Weigh the solute using the weigh by difference method
- In a beaker dissolve the solute using the solvent
- Pour the solution into a volumetric flask
- Rinse the beaker using the solution and add it to the flask
- Add solvent to the flask carefully until it reaches the graduation line
- Mix the solution thoroughly to ensure complete mixing
What are the four common state symbols?
- Solid (s)
- Liquid (l)
- Gaseous (g)
- Aqueous (aq)
What are the reasons for not obtaining 100% yield? (5)
● Reaction may be at equilibrium
● The reactants may be impure
● Side reactions could happen
● Reactants or products may be left behind while transferring
● Loss of products during separation and purification
What does atom economy tell us about?
The proportion of desired products compared with all the products formed in the reaction
Does 100% yield mean 100% atom economy?
No, even if all the reactants are converted into products, not all products of the reaction will be the required products
Which type of reaction has 100% atom economy?
Addition reactions (two or more reactants are combined to form a product)