10A. Equilibrium I [SET 1] Flashcards

1
Q

What can reversible reactions reach?

A

Dynamic euqillibrium

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

As the reactants are used up, what happens to the forward reaction?

A

It slows down

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

When is dynamic equilibrium achieved?

A

When the forwards reaction is going at exactly the same rate as the backwards reaction and the amounts of reactants and products aren’t changing

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What does dynamic equilibrium happen in?

A

A closed system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What is Kc?

A

The equilibrium constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What does Kc give you an idea of?

A

How far to the left or right the equilibrium is

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is a homogeneous system?

A

A system in which everything is in the same physical state

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What can Kc be worked out using?

A

The concentrations of reactants and products at equilibrium

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Which reactants and products are included in Kc for homogeneous equilibria?

A

All of them

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is the equation for Kc?

A

[products]/[reactants]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is a heterogeneous equilibria?

A

One in which not everything is in the same physical state

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is not included in the Kc expression for heterogeneous equilibria?

A

Pure liquids or solids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Why are solids not included in the Kc expression?

A

Because their concentration is constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Why are pure liquids not included in the Kc expression?

A

Because their concentration is constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Why aren’t catalysts included in the Kc expressions?

A

Because they don’t affect the equilibrium concentrations of the products or reactants

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

How do catalysts affect equilibrium?

A

They increase the rate at which equilibrium is reached

17
Q

What is Le Chatelier’s principle?

A

If there is a change in concentration, pressure or temperature, the equilibrium will move to help counteract the change

18
Q

If the position of equilibrium is altered, what will happen?

A

The amounts of products and reactants at equlibrium change

19
Q

What happens if the concentration of a reactant is increased?

A

The equilibrium shifts to the right to use up the extra reactants

20
Q

What happens if the concentration of a product is increased?

A

Equilibrium shifts to the left to remove the extra product

21
Q

What happens if the pressure is increased?

A

The equilibrium shifts to the side with fewer moles, reducing the pressure

22
Q

What does pressure affect?

A

Gases

23
Q

What happens if pressure is decreased?

A

Equilibrium shifts to the side with the most moles to raise the pressure

24
Q

What happens if temprature is increased?

A

The equilibrium shifts to the endothermic side to absorb the heat

25
Q

What happens if temperature is decreased?

A

The equilibrium shifts to the exothermic side to replace the heat

26
Q

What happens if the forward reaction is endothermic?

A

The reverse reaction is exothermic

27
Q

How are conditions chosen in industry?

A

As a compromise

28
Q

What are conditions chosen to produce?

A

A high rate and high yield

29
Q

How is ethanol made?

A

From ethene and steam

30
Q

What is the equation for ethanol production?

A

C2H4 + H2O –> C2H5OH

31
Q

What pressure is used for ethanol production?

A

60-70 atm

32
Q

What temperature is used for ethanol production?

A

300 degrees

33
Q

What catalyst is used for ethanol production?

A

Phosphoric acid

34
Q

Why is the temperature for ethanol production relatively low?

A

Because the forward reaction is exothermic, so lower temperatures favour it