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stay awhile, don't deny the violet chemistry > 2A. Bonding and Structure [SET 1] > Flashcards

2A. Bonding and Structure [SET 1] Flashcards

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1
Q

What is ionic bonding?

A

The strong electrostatic attraction between oppositely

charged ions

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2
Q

What effects does ionic radius have on the strength of ionic bonding?

A

The smaller the radius, the stronger the ionic bond

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3
Q

What effects do charges have on ionic bonding?

A

The greater the charge, the stronger the bond

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4
Q

How are ions formed?

A

By the loss (+) or gain (-) if electrons

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5
Q

What is a cation?

A

A positively charged ion

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6
Q

What is an anion?

A

A negatively charged ion

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7
Q

What does isoelectronic mean?

A

Two or more molecular entities that have the same number of electrons or a similar electron configuration

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8
Q

How does a positive charge affect atomic radius?

A

It gets smaller because it loses electrons from its outer shell

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9
Q

How does a negative charge affect ionic radius?

A

It gets larger because electrons are added to the outer shell

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10
Q

What are the trends in atomic radii for ions with different charges?

A

The larger the charge, the bigger the change in the ion’s size

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11
Q

How can the migration of ions be observed?

A

During electrolysis of coloured compounds

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12
Q

What does ionic migration prove?

A

The existence of ions

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13
Q

What are the melting/ boiling temperatures if ionic compounds like?

A

They’re high due to the dying bonds

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14
Q

What are ionic compounds like physically?

A

They’re hard, brittle, crystalline substances

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15
Q

How soluble are ionic compounds?

A

They’re soluble in water and other polar solvents but insoluble in non polar solvents

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16
Q

Do ionic compounds conduct?

A

Not when solid, because their ions cannot move away from their fixed positions, but they do conduct when melted or dissolved

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17
Q

What happens when ions reach the anode?

A

They lose electrons

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18
Q

What happens when ions reach the cathode?

A

They gain electrons

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19
Q

What is a covalent bond?

A

The strong electrostatic attraction between two nuclei and the shared pairs of electrons between them

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20
Q

What is a dative covalent bond?

A

One in which both the electrons in the bonding pair are provided by one atom

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21
Q

What do lone pairs of electrons do?

A
  • Affect the shapes of molecules
  • Are used to form dative covalent bonds
  • Are important in the chemical reactions of some compounds including water and ammonia
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22
Q

What is bond length?

A

The distance between the nuclei of two bonded atoms in a molecule

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23
Q

How can bond lengths be measured?

A

Using X-Ray diffraction when solid or Microwave spectroscopy when gaseous

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24
Q

What does bond length depend on?

A

The size of atoms involved and the number of pairs of electrons shared

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25
Q

Why do large atoms form longer bonds?

A

Because they have more electrons which shield the nuclei and reduce the attraction for the electron cloud.

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26
Q

Single bonds are…

A

…longer than double bonds, which are longer than triple bonds

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27
Q

Why are triple bonds shortest?

A

The nuclei can remain closer together if the shared electron cloud contains more electrons to overcome the repulsion of the nuclei

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28
Q

What is bond energy?

A

The energy required to break one mole of the bonds in a substance in the gaseous state

29
Q

Which bonds have greater bond strength?

A

Single bonds, they’re stronger and have greater bond energy.

30
Q

What is the shape of a simple molecule or ion determined by?

A

The repulsion between the electron pairs that surround the central atom

31
Q

What is electronegativity?

A

The ability of an atom to attract the bonding electrons in a covalent bond

32
Q

Ionic and covalent bonds are the extremes of…

A

…a continuum of bonding type

33
Q

Electronegativity differences lead to…

A

…bond polarity in bonds and molecules

34
Q

What are the 3 most electronegative elements?

A

Nitrogen, Oxygen, Flourine

35
Q

How do London Forces occur?

A

When non polar atoms or molecules meet and there are fleeting repulsion and attractions between the nuclei of the atoms and surrounding clouds of electrons

36
Q

What is polarisability?

A

An indication of the extent to which the electron cloud in a molecule or ion can be distorted by a nearby electric charge

37
Q

Bigger molecules with a larger number of electrons have a…

A

…higher polarisability and potential for temporary dipoles

38
Q

Why do the boiling temperatures rise down Group 7 and Group 0?

A

Because the atoms get bigger and have a greater polarisability and more electrons, so more London forces

39
Q

Why do branched alkanes have lower boiling points?

A

Because the have a smaller surface area and therefore

40
Q

What are the properties of simple molecular structures?

A

Usually gases, liquids or soft solids at room temperature
Have relatively low melting and boiling temperatures
Do not conduct electricity as thy contain neither ions or free electrons.
Usually soluble in non polar solvents

41
Q

What is electron pair repulsion theory?

A

That electron pairs n the utter shell of atoms and ions repel each other and get as far away as possible

42
Q

What is a bond angle?

A

The angle between who covalent bonds ina molecule or giant covalent structure

43
Q

What does isoeletronic mean?

A

Molecules and ions that have exactly the same number and arrangement of electrons

44
Q

What is the bond angle in a linear molecule?

A

180

45
Q

What is the bond angle in a trigonal planar?

A

120

46
Q

What is the bond angle in a tetrahedral molecule with no lone pairs?

A

109.5

47
Q

What are the bond angles in trigonal bipyramidal molecules?

A

90, 120, 180

48
Q

What are the bond angles in octahedral molecules?

A

90 and 180

49
Q

Ammonia and water are isoelectronic with…

A

…methane

50
Q

How are lone pairs held in relation to the central atom?

A

Closer than bonding pairs

51
Q

What is the strength of repulsion between electron pairs?

A

Lone pair - lone pair > Lone pair - bonding pair > bonding pair - bonding pair

52
Q

How do double or triple bonds affect shapes of molecules?

A

They don’t, they are treated as one bond and as a separate centre of negative charge

53
Q

What are polar covalent bonds?

A

Bonds between atoms of different elements. The shared electrons are drawn towards the atom with the stronger pull on the electrons.

54
Q

How does a big difference in electronegativity affect bonding type?

A

The bigger the difference in electronegativity, the more polar, and the more ionic a bond is.

55
Q

How does electronegativity change down a group?

A

It decreases

56
Q

Why is a polar liquid attracted to an object wth electrostatic charge?

A

Because polar molecules tend to move and rotate because the charge on one side of the molecule is attracted to the opposite charge of the object

57
Q

What are the essential requirements for hydrogen bonding?

A

A hydrogen atom covalently bonded to a highly electronegative atom
A lone pair of electrons on a second electronegative atom

58
Q

What is a saturated solution?

A

Contains as much of the solute as possible at a particular temperature

59
Q

What are the interactions involved in solubility?

A

The intermolecular forces between solute molecules
The intermolecular forces between solvent molecules
The intermolecular forces between solute and solvent molecules

60
Q

When does a molecular substance dissolve?

A

If the energy needed to break intermolecular forces and to separate the molecules in the solute and in the solvent is about the same as the energy released as the solute forms new intermolecular forces with the solvent

61
Q

What is a non-aqueous solvent?

A

Any solvent other than water

62
Q

What is hydration?

A

It takes place when water molecules bond to ions or add to molecules. Water molecules are polar o are attracted to both positive and negative ions

63
Q

What are allotropes?

A

Different forms of the same element in the same physical state

64
Q

What are the allotropes of carbon?

A

Diamond, graphite, fullerenes, graphemes

65
Q

Why does Diamond not conduct electricity?

A

The electrons in the cola lent bonds are not delocalised

66
Q

What are composites?

A

Two or metals combined to create a new material which has the desirable properties of both its constituents

67
Q

What are delocalised electrons?

A

Bonding electrons not fixed in a bond between two atoms. Free to move around and shared by many atoms.

68
Q

What is metallic bonding?

A

The strong electrostatic force of attraction between metal ions and delocalised electrons

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