5.2.2 Enthalpy and entropy Flashcards

1
Q

what is entropy

A

the dispersal of energy in a system.
Entropy increases as a system becomes more disordered

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2
Q

what leads to entropy becoming more positive

A

-change of state eg-from solid to liquid OR liquid to gas
-reactions that produce a gas
-increases in the number of moles
-dissolving (solid dissolving in water)
eg-NaCl(s)——->NaCl(aq)

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3
Q

what leads to entropy becoming more negative

A

-change in state (gas to liquid or liquid to solid)
-decrease in the number of moles
-randomness of particles decreases

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4
Q

how do you calculate entropy changes

A

deltaS=products-reactants
-use molar ratio

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5
Q

what are entropy units

A

Jk-1 mol-1

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6
Q

are standard entropies positive or negative

A

positive

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7
Q

which has a larger increase in entropy
A) Solid to liquid
b) Liquid to Gas

A

B) liquid to gas

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8
Q

what is Gibbs equation

A

deltaG=deltaH-TdeltaS

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9
Q

what must deltaG be for a reaction to be feasible

A

deltaG<0

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10
Q

units for Gibbs equation

A

delta S must be divide by 1000
degrees c in K by +273

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11
Q

how do you work out the temperature the reaction is feasible

A

T=deltaH/deltaS

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12
Q
A
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