5.1.1-how fast Flashcards

1
Q

what are the units for both average and instantaneous rate

A

moldm-3 s-1

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2
Q

define average rate

A

rate over a range of time

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3
Q

define instantaneous rate

A

rate at a precise point in time

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4
Q

how can you calculate average rate

A

change in concentration/
change in time
rate is the change in concentration of a reactant or product over time.

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5
Q

how do you calculate instantaneous rate

A

draw a tangent at that point and calculate the gradient

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6
Q

what is a general rate equation

A

rate=K(A)^M (B)^N

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7
Q

what are the units for concentration

A

mol dm-3

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8
Q

what is K and what is is dependant on

A

rate constant
dependant on temperature
as temperature increases rate increases so K must increase

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9
Q

finding units for k

A

in booklet

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10
Q

draw concentration time-graph for formation of product

A

in booklet

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11
Q

draw concentration time-graph for disappearing of reactant

A

in booklet

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12
Q

what is a first order reactant

A

direct proportionality between concentration of reactant and rate of reaction
eg-as one doubles so will the other.

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13
Q

draw the concentration-time graph for 1st order reactant

A

in booklet

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14
Q

draw the rate-concentration graph for 1st order reactant

A

in booklet

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15
Q

what is a 0th order reaction

A

no relationship between concentration of a reactant and rate of reaction

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16
Q

draw the concentration time graph for a 0th order reaction

A

in booklet

17
Q

draw the rate-concentration graph for 0th order reactant

A

in booklet

18
Q

what is a 2nd order reaction

A

rate is proportional to the concentration of a reactant squared

19
Q

draw the rate-concentration graph for 2nd order reactant

A

in booklet

20
Q

how do you calculate the overall order of reaction

A

add up the powers

21
Q

define half-life

A

Time taken for the concentration of a reactant to fall to half its original value

22
Q

What is the half life of the first order reaction

A

Constant

23
Q

What is an intermediate

A

Does not appear in the overall equation as it is used up in late steps

24
Q

What is the rate determining step

A

Slowest step in a multistep reaction

25
Q

if the concentration of a reactant appears in the rate equation where else must it appear

A

If the concentration of a reactant appears in the rare equation then it must be involved in the rate determining step

26
Q

how to calculate rate constant in a graph

A

K=ln(2)/half life

27
Q

what happens to K (rate constant) as temperature increase

A

-as temperature increases
-K increases and Ea

28
Q

express the arrhenius equation in terms of y=mx +c

A

lnk=-Ea/R X 1/T + lnA

29
Q

what units does this answer have

A

jmol-1 to need to divide by 1000 to turn into kJmol-1