4. b. Crude oil Flashcards
definition of crude oil
mixture of hydrocarbons
what method is used to separate crude oil
factional distillation
describe how fractional distillation separates crude oil into fractions
( rhyme = Only Grab The Tapas Lovely Soldier )
- oil heated = most turned into gas
- gases enter a fractionating column - liquid bitumen = drained of at the bottom
- temp gradient in fractionating column = hot at bottom + gradually gets cooler as you go up
- temp = lower than boiling point = substances condense
- long hydrocarbons = high boiling point = condense + drain out early near bottom
- Shorter Hydrocarbons = low boiling point = condense + drain out near top
what are the fractionating column products
rhyme = Ravenous Pigs Keenly Devour Lettuce For Breakfast
Refinery Gases Petrol Kerosene Diesel Lubricating Oil Fuel heavy oil Bitumen
uses of fractions
Refinery Gases = domestic heating +cooking
Petrol =- car fuel
Kerosene = plane fuel
Diesel = lorry / train fuel
Lubricating Oil =
Fuel heavy oil = Ship fuel ( + some power stations)
Bitumen = tarmacking roads
definition of a fuel
substance that when burned releases energy
what are the products of complete combustion of hydrocarbons with oxygen in air
carbon dioxide + water
what are the products of incomplete combustion of hydrocarbons with oxygen in air
carbon dioxide + water + carbon monoxide
why is carbon monoxide poisonous
can combine with haemoglobin in red blood cells and stop blood from carrying oxygen around the body
what does the high temp in car engines do
allow nitrogen + oxygen from air to react = oxides of nitrogen ( nitrogen monoxide + nitrogen dioxide )
what does the combustion of some impurities in hydrocarbons result in
sulphur dioxide
what is the danger of sulphur dioxide + nitrogen oxides
contribute to acid rain
when sulphur dioxide + nitrogen oxides mix with water vapour in clouds = dilute sulphuric acid + nitric acid = acid rain
how are long-chain alkanes converted to alkenes and shorter-chain alkanes
catalytic cracking
definition for cracking
splitting up long chain hydrocarbons
form of thermal decomposition ( breaking molecules down into simpler molecules by heating them.
what are the conditions required for cracking
catalyst = silica or alumina heat = 600-700*c
how is cracking carried out in industry
- vaporised hydrocarbons are passed over a powered catalyst ( silica / alumina ) at about 600-700*c
- alkane heated up till vaporised = break down when comes into contact with catalyst = produce mixture of shorter-chain alkanes + alkenes
why is cracking necessary
demand for shorter-chain hydrocarbons ( eg. octane in petrol) is much higher than for longer-chain hydrocarbons
to meet demand ( + achieve balance of supply & demand ) long chain hydrocarbons are split into more useful short-chain molecules
what are the properties of long-chain hydrocarbons ( boiling point + viscosity + colour )
boiling point = high
viscosity = viscous = thick + gloopy
colour = darker
what are the properties of shorter-chain hydrocarbons ( boiling point + viscosity + colour )
boiling point = low
viscosity = thinner
colour = paler