25.1-25.10 Flashcards

1
Q

alpha decay

A

alpha is the biggest (2 protons 2 neutrons)

alpha particle can be stopped by human skin

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2
Q

beta decay (three types)

A

proton to neutron (vice versa)

Beta-

Beta+

Electron capture

stronger than Alpha particle, but can be stopped by aluminum foil

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3
Q

Beta- decay (Standard BETA decay)

A

unstable nucleus has TOO MANY NEUTRONS

converts neutron to proton and electron

atomic number UP by 1, mass stays the same

Ca -> Sc + 0 -1 beta

what is emitted?

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4
Q

Beta+ decay (positron emission)

A

too few neutrons

proton becomes a neutron and a positron (identical to electron but with a positive charge)

atomic number DOWN by 1, no change in atomic mass

Co -> Fe + 0 +1 beta

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5
Q

electron capture

A

converts a proton into a neutron by capturing an electron

no change in mass number, but atomic number DOWN by 1

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6
Q

gamma decay

A

often accompanies other kinds of decay

stopped by lead or concrete

“gamma lead”

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7
Q

nuclear bind mass

A

LOSES mass when nucleus is formed

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8
Q

kilograms in an amu

A

1.66 ( 10^-27) kg

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9
Q

equation for nuclear binding energy

A

deltaMass (in amu) * 931.5 MeV

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10
Q

equation for energy of photon

A

E = hf

“Photons just wanna Have Fun”

fun is speed of c / wavelength

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11
Q

Planck’s constant

A

6.63 * 10^-34

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12
Q

electron has more energy when farther from nucleus!

A

like potential energy

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13
Q

En = (-2.178 * 10^-18) / n^2

A

Change in energy = E_final (n=1) - E_starting (n=2,3)

negative means energy is RELEASED

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14
Q

Bohr model contains 1 electron

A

1 ELECTRON = BOHRING

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15
Q

the p orbitals are like dumbbells

A

3 x,y,z

d has 5 orbital configurations (p has 3)

f has 7 orbital

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16
Q

diamagnetism/paramagnetism

A

diamagnetism - all electrons are spin paired

REPELLED by externally produced magnetic field

paramagnetism - not all spin paired (“WEIRDLY uneven”)

attracted into externally produced magnetic fields

17
Q

PERIOD and GROUP (and block)

A

PERIOD HORIZONTALLY (periods are like elipses…)

GROUP VERTICALLY (groups are like columns, stacks)

there are 4 blocks (s, p, d, f)

subtract 1 for d from period

subtract 2 for f from period

18
Q

3d

A

subtract down 1

4s2 3d10 …

THE FIRST D ROW IS ACTUALLY 3

19
Q

EXCEPTIONS: Chromium and Copper electron configuration

A

FILL the d orbitals (4->5, 9->10)

20
Q

EXCEPTIONS: Ag and Au

A

9->10
Ag = silver
Au = gold

FILL the d orbitals

21
Q

isoelectronic

A

iso = same electric shape

F- and Neon (same e- configurations)

22
Q

Transition metals lose s electrons before they lose d electrons

A

IMPORTANT - the s is valence electron since n > n-1

Transition metals are elements in the d block

ex. Ti is [Ar] 4s2 3d2

Ti2+ is [Ar] 3d2

23
Q

first two groups

A
Alkali metals (1 word)
Alkaline earth metals (2 words)
24
Q

halogens are powerful oxidizing agents

25
Metalloids
B Si Ge As Sb Te Po
26
atomic radius DECREASES going left to right (Zeff is higher to the right)
also decreases going up
27
X+ < X < X-
cations are smaller than anions
28
ionization energy = energy to remove an electron
INCREASES going right -- valence electrons are more tightly bound the 2nd ionization energy is always more than the 1st
29
electron affinity
halogens are VERY affinitive (energy is released = negative, increased stability) Very POSITIVE for noble gases and ALKALINE EARTH METALS because they need a new level or sublevel and this destabilizes ("they really don't want more electrons") affinities increase going RIGHT and UP (a general trend, does not include noble gases)
30
electronegativity
pulls electrons when forming a covalent bond (unfair sharing) F > O > N/Cl > Br > I > S > C/H
31
formal charge
valence electrons - 1/2 (electrons in bonds) - lone electrons
32
resonance structures
nonbonding electrons, double and triple bonds can move around
33
coordinate covalent bond
lone pair forms a bond on its own (obtains a formal positive charge) = LEWIS BASE LEWIS BASE = NUCELOPHILE LEWIS ACID = ELECTROPHILE = accepts electrons
34
coordinate covalent bond
lone pair forms a bond on its own (obtains a formal positive charge) = LEWIS BASE LEWIS BASE = NUCLEOPHILE LEWIS ACID = ELECTROPHILE = accepts electrons
35
oxidation states p. 668
keep working on it