230418 - Polymer Technology Flashcards
Pressure behavior during switchover points
Hydraulic pressure: Linear increase of the pressure then a steep rise until holding pressure.
Cavity pressure: Linear increase, then a non linear increment of the pressure and then decrease of it while the cooling down process.
Switchover point determination
Practical design of experiments to determine the precise point.
Too late switchover: tool damaging, flash.
Too early switchover: sink marks, non complete filling.
Total shrinkage time
16 - 24 hrs. After this time, the shrinkage and crystallization is over and the part can be gauged.
Shrinkage difference between reality and simulation can be very high (50%). Temperature distribution on surface of mold.
Parameters machine choosing
Plastification size (5x cavity, enough depth of the flights in the dosing part of the screw)
-> Clamping force (***) -> size of plates -> opening stroke (3Xdepth)
Incorrect machine selection
- Too big claping force: Expensive.
- Cycle time increases.
- Too high residence time in the plasticized damage, Too low, no homogenaization.
Injection or Holding pressure driven part
High injection speed to reach the injection pressure fast enough. The material will get cold soon.
Lot of material must be injected before the gate is sealed.
ratio: flow path length divided by the thickness. If ratio > 100: injection speed inflluenced part.
small flow path and big thickness
holding pressure influenced part
Estimation of clamping force
Projected area * cavity pressure * security factor (asimmetry, sliders)
The projected area should be symmetric in direction of injection.
Rheology
Science of deformation and flow of the body
Shear stress
shear stress = viscosity * shear velocity
? = ? * ?
For each polymer, you can determine the viscosity in terms of the temperature, and factors A,B, C (carreau theory)
Difference between dilatant, intrinsically viscous and newtonian fluid
Newtonian fluid: Linear relation between the velocity and the stress.
Dilatant: Small velocity increase requires a big stress increase.
Intrinsically viscous: Big velocity increase requires a small stress increase. Increase shear rate, decrease viscosity.
Pressure drop
inverselly proportional to the wall thickness
clamping pressure calculation
(pw): Reference values for flow path / wall thickness. Technical parts (1%), simple parts (2%) acceptable increase in weight
You can determine the clamping force in terms of the specified ratio.
If you have a bigger machine than the needed pressure, you can adjust the clamping force in hydraulical and electrical toggle machines
too small screw
inhumogeneus melt, unfused material.
Viscotiy fluctuations
too big screw
Hardly controllable injection process into the nozzle, material degradation,