2.1.2: Biological molecules Flashcards
Catabolic reaction
Large molecule broken down to smaller molecules e.g. hydrolysis
⟶ Energy given out (to surroundings)
Anabolic reaction
Smaller molecules built up to large molecule e.g. condensation reaction
⟶ Energy taken in (required)
Features of a hydrolysis reaction
- “Splitting with water”
- Catabolic
- Covalent bond broken
Features of a condensation reaction
- Water molecule produced
- Anabolic
- New covalent bond formed
Hydrogen bonding occurs when…
- Slightly negatively charged part of molecule contacts & attracts slightly positively charged part of molecule.
- Between H and O.
Individual hydrogen bonds are ____
weak but due to large numbers their effect can be big.
Effect of H-bonding on polymers
Strengthens and stabilises polymers.
Properties of water
- High SHC
- High latent heat of vaporisation
- Cohesion
- Surface tension
- Polar so can form H-bonds
- Expands when freezes
- Can act as solvent
Water’s high SHC
• Due to H-bonding, water molecules stick to one another
• Hard to separate molecules
• Higher boiling point than expected
• High SHC
⟶ Acts as a buffer to sudden temp. changes, keeps an environment stable
Water’s high latent heat of vaporisation
• Due to H-bonding, water molecules stick to one another
• Lots of energy needed to evaporate 1 gram of water
⟶ Sweating = effective cooling mechanism in mammals
Cohesion in water
Cohesion: tendency of water molecules to stick to each other
⟶ Allows water to be pulled up tube (xylem)
Surface tension in water
Body of water moves as one mass
• Water molecules at the edge of a body of water are pulled back in rather than escaping
⟶ Allows pond skater to skate across pond
Water’s density when freezing
• Water becomes less dense when it freezes
⟶ Ice floats, insulating water beneath and allowing organisms to survive
Water as a solvent
• Polar, interacts with other polar molecules
• Interaction of +ve and -ve charges keeps solute molecules apart hence it dissolves
⟶ Molecules in solution can move/react with other molecules –> water = basis for metabolic reactions
Functions of carbohydrates
- Energy source
- Energy store
- Structure (cellulose in wall)
- Parts of larger molecules (nucleic acids)
Generalised formula of a monosaccharide
C𝒏(H₂O)𝒏
Types of simple sugars
- Triose
- Pentose
- Hexose
Prefix = no. of carbons
Arrangements of glucose
- Chain
* Ring
Forms of glucose ring
Alpha
Beta
Alpha glucose
H above OH on C1
Beta glucose
OH above H on C1
Glycogen contains _ glucose
𝛂
Cellulose contains _ glucose
β
Glycosidic bond
Covalent bond between two monosaccharides
Sucrose
Glucose + fructose
Lactose
Glucose + galactose
Maltose
Glucose + glucose (both 𝛂)
Elements that make up carbohydrates
C
H
O
Elements that make up lipids
C
H
O
Elements that make up proteins
C H O N S
Elements that make up nucleic acids
C H O N P
Example of a pentose monosaccharide
Ribose
Carbohydrate polymers are stores of
potential energy
Large polysaccharides are ______ so do not affect ______
Large poysaccharides are insoluble so do not affect osmosis
Where is the glycosidic bond in amylose
1,4 glycosidic bond
Amylose arranged in coil so
very compact
Glycogen arrangement
- Branched (v. compact)
* Can be hydrolysed quickly
Where are the glycosidic bonds in glycogen?
- 1,4 glycosidic bond
* 1,6 linkage (forms branches)
Why is glycogen good for storage?
- Insoluble
- Very compact
- Large enough = doesn’t diffuse out easily
- Branches at 1,4; linkage at 1,6 –> lots of potential enzyme attachment, hydrolysis sites
Why high conc. glycogen = good athletic performance
- Glucose stored as glycogen
- Glucose used for respiration to produce ATP
- ATP needed for muscle contraction etc.
Conjugated proteins contain…
a prosthetic group