2.1 Rates of a Reaction Flashcards
Collision Theory
Atoms must collide in a specific alignment with suffiicent energy in order to react
Units of Concentration [ ]
mol per litre!
Rate equation
Rate = change in amount / time
Where is the max rate on a graph?
at the beginning usually
How to find rate at instant
- draw tangent to point
- extrapolate line so that values can be read
- use gradient equation (rise/run)
Average rate of change steps
- draw chord between two point
2. use gradient equation
When does the rate of reaction equal zero?
When the reaction has gone to completion
What factors influence the rate of a reaction?
- Concentration [ ]
- Temperature
- Pressure (gaseous systems ONLY)
- surface area (SA)
- addition of a catalyst
Which factors increase the frequency of collisions?
- Temperature (inc in Kinetic energy -> inc collisions)
- Concentration (inc collisions)
- Pressure (inc [ ] -> inc collisions)
- SA (inc [ ] -> inc collisions)
What factors change the proportional of particles with sufficient activation energy?
- Temperature (inc kinetic energy -> inc Ea)
2. Catalyst (orientates particles and dec Ea barrier)
What are enzymes?
Biological catalysts which work only with organic material
proteins which are specific for reaction
How do enzymes work?
Match the shape of the substance under going change
shape is determined by secondary bonding
conditions under which the enzyme will work must maintain the shape of the enzyme
What temperatures will enzyme not work?
Temps greater than 50 degrees
only in narrow pH range
How will activation energy (on energy profile) chnage with the addition of a catalyst?
Ea will be lower