2.1 Rates of a Reaction Flashcards

1
Q

Collision Theory

A

Atoms must collide in a specific alignment with suffiicent energy in order to react

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2
Q

Units of Concentration [ ]

A

mol per litre!

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3
Q

Rate equation

A

Rate = change in amount / time

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4
Q

Where is the max rate on a graph?

A

at the beginning usually

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5
Q

How to find rate at instant

A
  1. draw tangent to point
  2. extrapolate line so that values can be read
  3. use gradient equation (rise/run)
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6
Q

Average rate of change steps

A
  1. draw chord between two point

2. use gradient equation

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7
Q

When does the rate of reaction equal zero?

A

When the reaction has gone to completion

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8
Q

What factors influence the rate of a reaction?

A
  1. Concentration [ ]
  2. Temperature
  3. Pressure (gaseous systems ONLY)
  4. surface area (SA)
  5. addition of a catalyst
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9
Q

Which factors increase the frequency of collisions?

A
  1. Temperature (inc in Kinetic energy -> inc collisions)
  2. Concentration (inc collisions)
  3. Pressure (inc [ ] -> inc collisions)
  4. SA (inc [ ] -> inc collisions)
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10
Q

What factors change the proportional of particles with sufficient activation energy?

A
  1. Temperature (inc kinetic energy -> inc Ea)

2. Catalyst (orientates particles and dec Ea barrier)

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11
Q

What are enzymes?

A

Biological catalysts which work only with organic material

proteins which are specific for reaction

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12
Q

How do enzymes work?

A

Match the shape of the substance under going change
shape is determined by secondary bonding
conditions under which the enzyme will work must maintain the shape of the enzyme

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13
Q

What temperatures will enzyme not work?

A

Temps greater than 50 degrees

only in narrow pH range

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14
Q

How will activation energy (on energy profile) chnage with the addition of a catalyst?

A

Ea will be lower

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