1.3 lipids Flashcards
2 groups
Triglycerides & phospholipids
Triglycerides
Condensation of 1 molecule glycerol and 3 fatty acids
Ester bond
Formed in condensation reaction between glycerol and a fatty acid (RCOOH)
Triglyceride properties related to structure
Energy storage - high ratio of C-H bonds to C-C bonds. Long chains of hydrogen and carbon can be broken to form ATP
Metabolic water source - high ratio of H to O2 bonds
Insoluble - doesn’t affect water potential
Low mass
Phospholipids
One of the fatty acids of a triglyceride is substituted by a phosphate-containing group
Phospholipids properties related to structure
Form bilayer in cell membrane, allowing diffusion of non-polar/small molecules
Phosphate heads are hydrophilic so are attracted to water, orientate themselves towards water
Hydrophobic fatty acid orientate themselves away from water
Saturated
No C=C double bonds in hydrocarbon chain; all carbons fully saturated with hydrogen
Unsaturated
One or more C=C double bonds in hydrocarbon chain
Bend in structure due to double bond
Test for lipids
- Add ethanol and shake (dissolves lipids)
- Add water
- Positive: milky/cloudy white emulsion
Glycolipids
Special type of fat that is found in cell membranes
One of the fatty acids found in a triglyceride is substituted by a sugar or chain of sugars
Glycoproteins
Has sugar residues attached to its surface and always points towards tissue fluid (extracellular fluid)
Similarities between phospholipids and triglycerides
Fatty acids
Glycerol
ester bonds
C,H,O (P has phosphorus)
Insoluble in water as non-polar
How are lipids different to carbohydrates
More O2 in carbohydrates
Lipids have a large number of C-H bonds