12. THERMODYNAMICS II Flashcards
- What are the three physical states that matter exists in?
- solid
- liquid
- vapor
- What can change about a material when it absorbs heat?
- its physical state
- What is Melting?
Give an example.
- it is when a solid changes from the solid state
- to the liquid state
- the process requires energy
- this is because the molecules of a solid are found in a rigid structure
- they are not free to move without added energy
- EG: melting an ice cube to form liquid water
- What is Freezing?
- it is when a liquid is frozen to form a solid
- it is the reverse of melting
- it requires energy to be removed from the liquid
- this is so that the molecule can settle into a rigid structure
- What is Vaporizing?
Give an example.
- it is changing a substance from its liquid state to its vapour (gas) state
- this process requires energy
- this is because the molecules must be freed from their clusters
- boiling liquid water
- this transforms it to water vapour (or steam)
- What is steam?
- it is the gas of individual water molecules
- What is Condensing?
- it is when a gas is condensed to form a liquid
- it is the reverse of vaporizing
- it requires energy to be removed from the gas
- this allows the molecules of the gas to cluster instead of flying away from one another
- What is a material’s heat of transformation?
What is another word for the heat of the transformation?
- it is the amount of energy required per unit mass
- to change the state of a particular material
- it does NOT change the temperature
- the Latent Heat
- What is the symbol for heat of transformation?
- L
- What is the formula to work out the heat of the transformation?
Q= L x m
- Q= the measure of the heat energy (J/kg)
- L= constant
= it is the latent heat dependent on the material
= it is measured in joules - m = mass (kg)
- What is the Heat of Vaporization (Lv)?
- it is the amount of energy per unit mass
- that must be added to vaporize a liquid
- OR that must be removed to condense a gas
- What is the Heat of Fusion (Lf)?
- it is the amount of energy per unit mass
- that must be added to melt a solid
- OR that must be removed to freeze a liquid
- Why is an effective mode of body heat loss important?
- all our metabolism goes into making heat
- very little of our metabolism goes into useful mechanical work
- our body temperature would rise very quickly if we did not have effective modes of heat loss
- What are the five modes of heat loss?
- Radiation
- Convection
- Conduction
- Evaporation of sweat
- Evaporation of water through breathing
- What is radiation loss?
What percentage of heat is lost through this?
- it is the loss of heat by the emission of electromagnetic radiation
- 54%-60% heat loss
- What is convection?
What percentage of heat is lost through this?
- the loss of radiated heat
- it is removed by moving air
- around 25% of heat is lost
- What is conduction?
What percentage of heat is lost through this?
- it is the direct transfer of heat through contact
- around 25% of heat is lost
- What is the Evaporation of sweat?
What percentage of heat is lost through this?
- it is the loss of heat by the evaporation of water
- around 7% of heat is lost
- What is the Evaporation of water through breathing?
What percentage of heat is lost through this?
- it is the loss of heat by the evaporation of water
- around 14% of heat is lost
- What do the magnitude and importance of the four modes of heat loss depend on?
- clothing
- environment
- surroundings
- What is thermal radiation?
- it is the exchange of energy as heat between an object and its environment
- this is done via electromagnetic waves
- What happens when you stand near a fire?
- you are warmed
- you absorb the thermal radiation from the fire
- your thermal energy increases as the fire’s thermal energy decreases
- there is no medium required for the heat transfer via radiation
- Why is there no medium required for heat transfer that is accomplished through radiation?
- radiation can travel through a vacuum
- According to Planck’s Law, what do all objects at a temperature (T) emit?
- they emit Thermal radiation
- What is essential in Planck’s law?
- the presence of a black body
- What is a Black Body?
List three characteristics.
- It is a body that absorbs all the thermal radiation falling onto it
- At thermal equilibrium, it emits as much energy as it absorbs
- It is a good absorber of radiation
and a good emitter of radiation
- What is Radiation incident?
- the unintended exposure of an individual to radiation
- What are the three types/components of Radiation Incident?
- reflection of the radiation by the object
- absorption of the radiation into the object
- transmission of radiation through the object
- What is Emissivity?
- it is the fraction of the energy incident on the object
that is absorbed
- What can be said about the Emissivity of a shiny, metallic, reflective surface?
- it is very low
- less than 0.1
NB: emissivity exists on a scale from 0 to 1
- What can be said about the Emissivity of dull, black surfaces?
- they have the highest emissivity
- between 0.9 and 1
- What is the unit for Emissivity?
- ε
- What is the formula to calculate emissivity?
P = 𝑒. σ . A . T⁴
- P= the radiated power (Watts)
- 𝑒 = emissivity
= it is a ratio
= it has no units - σ= the Stefan - Boltzman Constant
= 5.67 x 10 ⎺⁸ (W/m².K⁴) - A = the surface area (m²)
- T = the temperature (Kelvins)
- What does the Stefan Boltzman Law represent?
How can this be expressed in a formula?
- the energy per second (power) radiated by the surface
- ▵Q / ▵t
- Where does the body receive radiant energy from?
- the surrounding objects
- What unit of measurement can we find to calculate the approximate difference between the energy radiated by the body AND the energy absorbed from the radiation from the surroundings?
- we can look for Hr
- this is the rate of energy loss or gain
- it is another way of writing power
- it is measured in watts
- What is the formula for Hr?
- Hr = Power (watts)
- Kr = constant
= it is a parameter
= it is about 2.1 x 10⁴ (J/m²hr°C)
= it can also be written as 5.0 kcal/m²hr°C - Ar = the effective body surface area (m²)
= it is what is emitting the radiation - 𝑒 = surface emissivity
- (Ts - Tw) = difference in temperature
= this can be in any unit - Ts = the skin temperature (°C)
- Tw = the surrounding walls temperature (°C)
- When does Conduction occur?
- when the thermal energy moves through a material as a result of collisions
- these collisions happen between free electrons, ions, atoms and molecules of the material
- What can be said about the average kinetic energy of a hotter substance?
- it is higher
- What happens with regards to energy between materials in contact with one another?
- the higher energy atoms in the warmer substances transfer energy to the lower energy atoms in the cooler substances
- this is a result of atomic collisions between the two
- this allows heat to flow from hot to cold
- How would we calculate the temperature difference?
▵T = T1 - T 2
- What is the temperature gradient?
- the ▵T / ▵ x
- ▵T = the change in temperature
= the unit is not important - ▵x = the thickness of the body
- this is the rate of change of temperature with distance
- How would we work out the quantity of heat (▵Q) that is transmitted from Face 1 to Face 2 of the body for a given time (▵t)?
▵Q / ▵t = kT x A x ▵T/▵x
kT= this is the thermal conductivity of the material
= this depends on the material of the body
= it has a unit of W/m.K
A= the cross sectional area (m²)
▵T = the change in temperature
= the unit is not important
▵x = thickness
= change in distance (m)
- What is another way of working out ▵Q / ▵t?
▵Q / ▵t = h x A x ▵T
- h = the coefficient of the conduction heat transfer
- A = the cross sectional area (m²)
- ▵T = change in temperature
= the unit is not important
- How else can we calculate the coefficient of conduction heat transfer (h)?
h = kT / ▵x
- kT= the thermal conductivity
= W/m.K. - ▵x= thickness of the body
= the distance (m)
- What is the flame of a candle classified as?
- it is convection
- it is this convection that is transporting the thermal energy upwards
- this energy transfer occurs when:
- a fluid (air)
- encounters an object (match)
- with a higher temperature than that of the fluid
-the temperature of the part of the fluid that is in contact with the hot object increases
- the fluid expands
- it becomes less dense
- it is now lighter than the surrounding cooler fluid
- buoyant forces cause it to then rise
- How can the heat loss due to Convection/Conduction be worked out?
- we must find the heat loss due to convection (Hc)
- this is the rate of energy transfer
- it is another way of working out power
- it has a unit of Watts
- What is the formula for working out Hc?
Hc = Kc x Ac x (Ts - Ta)
- Hc = the heat loss due to convection
= power (in watts) - Kc = a parameter
= it depends on the movement of the air= when the speed of the air is less than 0.2 m/s = it then has a value of 3.1 W/m²K
- Ac = the effective body surface area (m²)
- Ts = the skin temperature in Kelvins
- Ta = the air temperature in Kelvins
- When is the Convective heat loss greater?
- when the air is moving
- the Convective heat loss is much smaller when the air is still
- What is Convection within the body called?
- the flow of blood
- What does the flow of blood change?
What does it not affect?
- it changes the distribution of the temperature within the body
- it does not affect the average temperature of the body
- What is the normal core body temperature?
- 36.5° - 37.5°
- How much does the core temperature generally change during the waking hours?
- it increases by 0.5 ° C
- What is an example of how well the body controls its temperature?
- the nude body can maintain its core temperature (between 36°C and 38°C) for several hours
- it can do this within environmental temperature changes that range from 21°C and 54°C in dry air
- What is the correlation between temperature deviation from the normal body temperature, and exposure time?
- the larger the temperature deviation from the normal body temperature
- the shorter the maximum possible exposure time until death
- What is the Convection Temperature for a naked adult man as compared to a naked baby?
(if we have minimal air movement)
- naked adult man = 26°C
- naked baby = 35°C
- Where is the Thermoneutral Zone located?
(the zone of minimal metabolism)
- it is between the Tc (Convection Temperature)
AND - the Th (Hypothermia Temperature)
- What happens below the Tc (convection temperature)?
- the heat loss increases
- this is due to convection and radiation
- What increases metabolism?
- increases in muscle tension
- shivering
- What increases muscle tension and shivering?
- increases in the difference between the body temperature and the environmental temperatures
- What happens to the core body temperature at low temperatures?
- it cannot be maintained
- there is cooling
- hypothermia develops
- How does heat loss happen above Th
(Hypothermia Temperature)?
- it is dominated by evaporation
- Give the core temperature ranges for each of the following:
63.1: Mild Hypothermia
63.2: Moderate Hypothermia
63.3: Severe Hypothermia
63.1: 32°C- 35°C
63.2: 28°C - 32°C
63.3: less than 28°C
- Which temperature is usually lower than the Core
temperature (37°C)?
- the temperature of the body skin (Tskin)
- this usually sits at 34°C
- What is Thermoregulation?
- it is the maintenance of a constant core body temperature in an organism
- both humans and other warm-blooded organisms thermoregulate
- What is the term given to warm-blooded organisms?
- homeotherms
- What aspects of the human body allow it to thermoregulate?
- the human body has temperature-sensitive receptors
- these are located in the skin, hypothalamus, midbrain, spinal cord and the abdominal cavity
- these thermoreceptors sense either hot and cold
- most areas of the human body have both kinds of thermoreceptors
- the sensors send information to the hypothalamus in the brain
- this controls the body’s response to the stimuli
- How do the blood vessels in the body react when the internal body temperature or the skin temperature gets too low?
- these blood vessels are found adjacent to the skin
- the blood vessel becomes smaller
- it constricts
- it reduces the blood flow from the core to the surface
- this process is called Vasoconstriction
- What are the effects of Vasoconstriction?
- it reduces the rate of heat loss from the skin surface
- it allows the skin to get colder
- What is Vasodilation and when is it used?
- it is when the blood vessel increases in size
- it expands
- this happens when there is a need to increase the rate of heat loss
- this happens when the body is too hot
- the blood supply to the skin is increased by Vasodilation
- this increases the blood flow in the skin
- this reduces the blood pressure
- What is Piloerection?
- it is when the fine body hairs stand on end
- this is an attempt to reduce convective heat loss from the skin
- the raising of the air is intended to create a stationary layer of air between the skin and the surroundings
- What is Shivering?
- it is a physiological response to cold temperatures
- cold signals are transmitted to the hypothalamus
- they trigger the reflex
- the body muscles begin to make small movements to use up some metabolic energy
- this generates thermal energy
- What is Perspiration/ Sweating?
- it is a very effective cooling mechanism
- this is because the Latent Heat (L) of evaporation of water is high
- heat loss that is caused by the evaporation of the liquid from the skin is the only way we can lose heat when the air is above 37°C
- the human body has sweat glands in the skin
- these excrete fluid
- it is mainly water
- it has some dissolved salts in it
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary?
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes
- Read through this summary.
Does everything make sense?
- yes